Qiwei Wang , Lu Jiang , Junlong Li , Zelin Sun , Wai-Yeung Wong
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引用次数: 0
Abstract
Development of carbon-rich organometallic systems containing rigid, π-conjugated fragments is a hot research topic. Construction of donor-acceptor skeleton with the thiophene donor group and the acceptor units such as benzothiazole and fluorenone can usually improve the electronic properties of the resulting organic materials. New nanoscale-sized organometallic acetylide polymers of platinum(II) bridged by bis(thienyleneethynylene)-benzothiadiazole moiety P1 and bis(thienyleneethynylene)-fluorenone moiety P2 have been synthesized in which an additional triple bond was inserted between the thiophene ring and the acceptor unit in the central spacer unit. The photophysical and electrochemical properties of P1 and P2 were investigated and compared with those of their model diplatinum(II) complexes and related polymers with other heteroaromatic spacers.
期刊介绍：
The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds.
Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome.
The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.
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