The recent advances of copper(II)-β-cyclodextrin complex as a practical catalyst system for various organic conversions: A review

IF 2.1 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Journal of Organometallic Chemistry Pub Date : 2025-01-09 DOI:10.1016/j.jorganchem.2025.123509

Sara Payamifar , Majid Abdouss , Ahmad Poursattar Marjani

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Abstract

Nowadays, a considerable amount of research is focused on cyclodextrin chemistry because it is economically and environmentally helpful; also, they are eco-friendly biomimetic materials, water-soluble, low-price, commercially available, easily functionalized, and non-toxic. These particular properties make cyclodextrin (CD) an appealing and invaluable field for study. β-CD can make host-guest complexes by non-covalent bonding, leading to highly selectively catalyzed chemical reactions. Indeed, β-CD has been vastly applied as a green nanocatalyst for organic conversions. In this regard, Cu(II)-β-CD is a dinuclear complex with great stability constants that recently received massive attention in organic chemistry. Cu(II)-β-CD is easily accessible and structurally simple and can be a promising catalyst in different organic conversions. This review concentrates on using copper(II)-β-CD catalyst as an advantageous catalyst in the diverse organic reactions and summary articles.

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铜(II)-β-环糊精配合物作为各种有机转化的实用催化剂体系的研究进展

由于环糊精具有经济、环保的优点，目前对其进行了大量的研究；此外，它们是一种生态友好型仿生材料，具有水溶性、价格低廉、易商品化、易功能化、无毒等特点。这些特殊的性质使环糊精（CD）成为一个有吸引力和宝贵的研究领域。β-CD可以通过非共价键形成主客体配合物，导致高度选择性催化的化学反应。事实上，β-CD已经作为一种绿色纳米催化剂广泛应用于有机转化。Cu(II)-β-CD是一种稳定常数大的双核配合物，近年来在有机化学领域受到广泛关注。Cu(II)-β-CD易于获取，结构简单，在不同的有机转化中具有很好的应用前景。本文综述了铜(II)-β-CD催化剂作为一种优势催化剂在各种有机反应中的应用。

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来源期刊

Journal of Organometallic Chemistry 化学-无机化学与核化学

CiteScore

4.40

自引率

8.70%

发文量

221

审稿时长

36 days

期刊介绍： The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.

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