Effect of Annealing on the Pyro-Phototronic Behaviour in Al/nanostructured PS-ML: p+-Si Schottky Photovoltaic Device

IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Silicon Pub Date : 2024-12-05 DOI:10.1007/s12633-024-03204-4
Jonmani Rabha, Mintu Das, Saponjeet Borah, Deepali Sarkar
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Abstract

In the present study, effect of annealing in Al/nanostructured porous silicon multilayer (PS-ML): p+-Si Schottky photovoltaic device is observed for the behavioural change in its pyro-phototronic and corresponding photovoltaic effect. Under UV (365 nm) illumination condition, the as-prepared device shows maximum enhancement and increment factor of 31.16% and 186% at \(0.5V\) compared to the devices annealed at temperatures \(50^\circ C\) and \(100^\circ C\) respectively. However, the coupling between pyro-phototronic and photovoltaic effect remains effective only for the device annealed up to \(100^\circ C\). On further elevating the annealing temperature to \(150^\circ C\), the pyro-phototronic effect diminishes while photovoltaic is still retained. The device treated at \(150^\circ C\) shows enhancement in open circuit voltage (\({V}_{oc}\)) value of \(\pm 841 mV\) with large value of fill factor (FF) of \(27\%\) and power conversion efficiency (PCE) of \(9.63\%\) and \(6.36\%\) for upward and downward poling respectively. While on elevating the annealing temperature to \(200^\circ C\), device performance degrades.

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退火对铝/纳米结构 PS-ML:p+-硅肖特基光伏器件热释光行为的影响
在本研究中,观察了Al/纳米结构多孔硅多层(PS-ML): p+-Si肖特基光伏器件的退火效应,观察了其热光电子行为的变化和相应的光伏效应。在紫外(365 nm)光照条件下,所制备的器件的最大增强和增量因子为31.16% and 186% at \(0.5V\) compared to the devices annealed at temperatures \(50^\circ C\) and \(100^\circ C\) respectively. However, the coupling between pyro-phototronic and photovoltaic effect remains effective only for the device annealed up to \(100^\circ C\). On further elevating the annealing temperature to \(150^\circ C\), the pyro-phototronic effect diminishes while photovoltaic is still retained. The device treated at \(150^\circ C\) shows enhancement in open circuit voltage (\({V}_{oc}\)) value of \(\pm 841 mV\) with large value of fill factor (FF) of \(27\%\) and power conversion efficiency (PCE) of \(9.63\%\) and \(6.36\%\) for upward and downward poling respectively. While on elevating the annealing temperature to \(200^\circ C\), device performance degrades.
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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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