{"title":"Electrochemical Esterification Reaction of Alkyne Aldehyde with Alcohols Mediated by Carbene and Iodine","authors":"Kai-Wei Chen, Guo-Ao Wang, Fei-Hu Cui, Shu-Hui Li, Ying-Ming Pan, Hai-Tao Tang","doi":"10.1002/cctc.202401418","DOIUrl":null,"url":null,"abstract":"<p>A new type of alkyne esterification was developed under electrochemical conditions using alkyne aldehydes and alcohol compounds as starting materials and carbene and iodine as mediators. Through this method, external oxidants and transition metals are excluded and the alkyne bond is fully preserved. This approach is compatible with a wide range of substrates and various functional groups and provides a green and mild new route for directly converting alkyne aldehydes into alkyne esters.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 3","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cctc.202401418","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
A new type of alkyne esterification was developed under electrochemical conditions using alkyne aldehydes and alcohol compounds as starting materials and carbene and iodine as mediators. Through this method, external oxidants and transition metals are excluded and the alkyne bond is fully preserved. This approach is compatible with a wide range of substrates and various functional groups and provides a green and mild new route for directly converting alkyne aldehydes into alkyne esters.
期刊介绍：
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
