Stearic acid/CNT-wrapped superhydrophobic/oleophilic sponge with Joule-heating effect for efficient removal of crude oil

IF 3.6 2区 物理与天体物理 Q2 PHYSICS, APPLIED Applied Physics Letters Pub Date : 2025-02-07 DOI:10.1063/5.0241597
Duanhong Yan, Kai Yin, Yao Liu, Pengyu Yang, Jun He, Yin Huang, Fan Zhang, Christopher J. Arnusch
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Abstract

Crude oil spill accidents cause extreme environmental damage, with huge economic costs that include the loss of oil resources. Despite the advances in conventional oil spill cleanup technology, such as dispersants, absorbents, and skimmers, there is still a need for more efficient solutions. In this study, we introduce a Joule-heated stearic acid/carbon nanotube-wrapped polyurethane sponge (SCPU) for rapid and all-weather recovery of leaked crude oil. SCPU is both hydrophobic and oleophilic and is electrically conductive. When 6 V were applied across the SCPU, the surface temperature increased to 146 °C within 70 s, which reduced the viscosity of crude oil and shortened the recovery time by over 99%. In addition, the Joule-heated SCPU can continuously recover crude oil floating on the water surface when connected to a peristaltic pump. This Joule-heated SCPU has a high crude oil adsorption capacity, a scalable preparation method, and is mechanically stable, and thus is expected to provide an efficient and practical solution for responding to crude oil spill accidents.
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硬脂酸/碳纳米管包裹的超疏水/亲油海绵,具有焦耳加热效应,可有效去除原油
原油泄漏事故造成极端的环境破坏,造成包括石油资源损失在内的巨大经济损失。尽管传统的溢油清理技术(如分散剂、吸收剂和撇油器)取得了进步,但仍然需要更有效的解决方案。在这项研究中,我们介绍了一种焦耳加热硬脂酸/碳纳米管包裹的聚氨酯海绵(SCPU),用于快速全天候回收泄漏的原油。SCPU既疏水又亲油,并且具有导电性。当SCPU上施加6 V时,表面温度在70 s内升至146℃,降低了原油粘度,缩短了99%以上的采收率。此外,当与蠕动泵连接时,焦耳加热的SCPU可以连续回收漂浮在水面上的原油。这种焦耳加热的SCPU具有高原油吸附能力、可扩展的制备方法和机械稳定性,因此有望为应对原油泄漏事故提供高效实用的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Applied Physics Letters
Applied Physics Letters 物理-物理:应用
CiteScore
6.40
自引率
10.00%
发文量
1821
审稿时长
1.6 months
期刊介绍: Applied Physics Letters (APL) features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination of key data and new physical insights, APL offers prompt publication of new experimental and theoretical papers reporting applications of physics phenomena to all branches of science, engineering, and modern technology. In addition to regular articles, the journal also publishes invited Fast Track, Perspectives, and in-depth Editorials which report on cutting-edge areas in applied physics. APL Perspectives are forward-looking invited letters which highlight recent developments or discoveries. Emphasis is placed on very recent developments, potentially disruptive technologies, open questions and possible solutions. They also include a mini-roadmap detailing where the community should direct efforts in order for the phenomena to be viable for application and the challenges associated with meeting that performance threshold. Perspectives are characterized by personal viewpoints and opinions of recognized experts in the field. Fast Track articles are invited original research articles that report results that are particularly novel and important or provide a significant advancement in an emerging field. Because of the urgency and scientific importance of the work, the peer review process is accelerated. If, during the review process, it becomes apparent that the paper does not meet the Fast Track criterion, it is returned to a normal track.
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