A New Type Microwave Absorption Materials: Metal–Organic-Frameworks (MOFs) Used as Non-Conductive Material Combination with P-C-800

IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Advanced Electronic Materials Pub Date : 2025-02-08 DOI:10.1002/aelm.202400738
Guodong Han, Song Zhao, Sai Sui, Bo Feng, Yudeng Wang, Junxiang Zhou, Zhuolun Li, Xiaoxia Tian, Yuxiang Jia, Jiafu Wang, Shaobo Qu
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Abstract

Metal–Organic-Frameworks (MOFs) are commonly used as microwave-absorbing materials after pyrolysis treatment. Rare researchers treat MOFs as non-conductive materials and use them as absorbing materials directly. In this paper, MOFs@P-C-800 composite materials are prepared adopt to hydrothermal and ultrasonic dispersion methods by regulating the morphological characteristics of MOFs and the content of P-C-800. As for the Co-BDC-P-C-800, the maximum reflection loss reaches −18.4 dB at 14.29 GHz and the effective absorption bandwidth (EAB) achieves 3.87 GHz from 13.5 to 17.37 GHz. After the contents of P-C-800 is adjusted, the Co-BDC-P-C-800 (0.05 g) exhibited excellent microwave absorption performance, the maximum RL value of −60 dB at 13 GHz with a thickness of 2.0 mm, and the EAB achieves 5.91 GHz from 12.02 to 17.93 GHz. This paper not only provides new application direction for MOFs, but also offers a promising direction for the research and development of absorbing materials.

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一种新型微波吸收材料:与P‐C‐800结合作为非导电材料的金属有机骨架
金属有机骨架(MOFs)是一种经过热解处理的微波吸收材料。很少有研究者将mof作为非导电材料直接用作吸波材料。本文通过调节mof的形态特征和P‐C‐800的含量,采用水热和超声分散的方法制备了MOFs@P‐C‐800复合材料。Co - BDC - P - C - 800在14.29 GHz处的最大反射损耗达到- 18.4 dB,在13.5 ~ 17.37 GHz处的有效吸收带宽(EAB)达到3.87 GHz。调整P‐C‐800的含量后,Co‐BDC‐P‐C‐800 (0.05 g)表现出优异的微波吸收性能,厚度为2.0 mm的Co‐BDC‐P‐C‐800在13 GHz处的最大RL值为−60 dB, EAB在12.02 ~ 17.93 GHz范围内达到5.91 GHz。本文不仅为MOFs提供了新的应用方向,也为吸波材料的研究与开发提供了一个有前景的方向。
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来源期刊
Advanced Electronic Materials
Advanced Electronic Materials NANOSCIENCE & NANOTECHNOLOGYMATERIALS SCIE-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
11.00
自引率
3.20%
发文量
433
期刊介绍: Advanced Electronic Materials is an interdisciplinary forum for peer-reviewed, high-quality, high-impact research in the fields of materials science, physics, and engineering of electronic and magnetic materials. It includes research on physics and physical properties of electronic and magnetic materials, spintronics, electronics, device physics and engineering, micro- and nano-electromechanical systems, and organic electronics, in addition to fundamental research.
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