Covalent organic framework nanomaterials: Syntheses, architectures, and applications

Abstract

Covalent Organic Frameworks (COFs) are characterized by high thermochemical stability, low backbone density, well-controlled physical and chemical properties, large specific surface volume and porosity, permanently open pore structure, and various synthesis strategies. These remarkable attributes confer COFs with significant potential for a myriad of applications ranging from catalysis technology, gas separation and storage, optoelectronic materials, environmental and energy sciences, and biomedical development. There are many synthetic design methods for COF materials, and dynamic covalent chemistry is the scientific basis of COF materials-oriented design, which gives the error correction ability of the covalent assembly process, and is the key to obtaining crystallization and stability at the same time. However, “crystallinity” and “stability” in the synthesis and preparation of COF materials are often like “You can't have your cake and eat it, too”: on the one hand, the reversible covalent bonds used in the synthesis of highly crystalline COF framework are easy to decompose under extreme conditions, which greatly limits its application scenarios; On the other hand, although highly stable COF materials can be prepared by using irreversible covalent bonds, it is usually poor crystalline and difficult to have high performance. In addition, the strict deoxygenation operation required for synthesizing COF materials also limits its macro preparation and large-scale application. Therefore, the synthesis strategy and efficient preparation of highly stable and crystalline COF materials are a major obstacle to the practical application of this field. This paper describes the four structures of COF materials, as well as their synthesis methods, electrical energy-storing electrocatalysis, and significant environmental protection applications. The future directions, prospects, and possible barriers to the development of these materials are envisioned in.