Corrosion resistance of PbSrSnAl positive grid alloys for lead-acid batteries

IF 5.6 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2025-04-10 Epub Date: 2025-02-10 DOI:10.1016/j.electacta.2025.145835
Fangzhao Pang , Xiang Chen , Xinyu Li , Bingbing Wang , Yongxin Wu , Yuhua Xiao , Xin Qu , Xiaowei Liu , Shuaibo Gao , Dihua Wang , Huayi Yin
{"title":"Corrosion resistance of PbSrSnAl positive grid alloys for lead-acid batteries","authors":"Fangzhao Pang ,&nbsp;Xiang Chen ,&nbsp;Xinyu Li ,&nbsp;Bingbing Wang ,&nbsp;Yongxin Wu ,&nbsp;Yuhua Xiao ,&nbsp;Xin Qu ,&nbsp;Xiaowei Liu ,&nbsp;Shuaibo Gao ,&nbsp;Dihua Wang ,&nbsp;Huayi Yin","doi":"10.1016/j.electacta.2025.145835","DOIUrl":null,"url":null,"abstract":"<div><div>The corrosion of positive grids limits the lifetime of lead-acid batteries. In this study, the corrosion behaviors of PbSrSnAl alloys were investigated. The addition of Sr significantly increases the strain of the grid alloy, and elevates the oxygen evolution potential is raised from 1.863 V to 1.879 V. In addition, the corrosion rate of the PbSrSnAl alloy is reduced from 0.432 to 0.396 mg h<sup>−1</sup> cm<sup>−2</sup>, as Sr changes the microstructure of the corrosion layer on the alloy surface. This study proposes a promising strontium-containing lead alloy that could extend the working life of lead-acid batteries.</div></div>","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":"519 ","pages":"Article 145835"},"PeriodicalIF":5.6000,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013468625001987","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/10 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

Abstract

The corrosion of positive grids limits the lifetime of lead-acid batteries. In this study, the corrosion behaviors of PbSrSnAl alloys were investigated. The addition of Sr significantly increases the strain of the grid alloy, and elevates the oxygen evolution potential is raised from 1.863 V to 1.879 V. In addition, the corrosion rate of the PbSrSnAl alloy is reduced from 0.432 to 0.396 mg h−1 cm−2, as Sr changes the microstructure of the corrosion layer on the alloy surface. This study proposes a promising strontium-containing lead alloy that could extend the working life of lead-acid batteries.

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
铅酸电池用PbSrSnAl正栅合金的耐腐蚀性能
正极栅的腐蚀限制了铅酸电池的使用寿命。本研究对PbSrSnAl合金的腐蚀行为进行了研究。Sr的加入显著提高了栅格合金的应变,使析氧电位由1.863 V提高到1.879 V。此外,由于锶改变了合金表面腐蚀层的组织,PbSrSnAl合金的腐蚀速率从0.432 mg h−1 cm−2降低到0.396 mg h−1 cm−2。本研究提出了一种有望延长铅酸电池使用寿命的含锶铅合金。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
期刊最新文献
Metal termination of Pd(111) enables selective electrochemical nitrogen oxidation reaction under anodic polarization Redox-active low transition temperature mixtures of propylene glycol and iodide salts as electrolytes for hybrid electrochemical capacitors Mechanistic insights into LYNF perovskite zinc–air battery Harnessing oxygen evolution for electrochemiluminescence enhancement using deep eutectic solvent-assisted Co LDH Nanosheets: Toward sensitive detection of cardiac troponin I Advanced Mn-doped PPy/GO nanocomposite cathode for efficient photoelectrochemical degradation of capecitabine in wastewater: Optimization and mechanistic insights
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1