The effects of tungsten content on the mechanical behavior, ignition and energy-release characteristics of short-tungsten-fibers/Zr-BMGCs under dynamic loading

IF 7.9 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials & Design Pub Date : 2025-03-01 Epub Date: 2025-02-08 DOI:10.1016/j.matdes.2025.113703
Xin Yu, Jianbin Li, Xiqiang Gai, Chong Chen, Zhenxiong Wang, Xin Zhao, Hongwei Zhao, Kaichuang Zhang
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Abstract

The short tungsten fibers/Zr-based bulk metallic glass composites (SWF/Zr-BMGCs) were prepared by melt infiltration casting. The effects of tungsten content on mechanical properties and energy-release characteristics under dynamic loading of Zr59.62Cu14.4Ni12Al10Nb3Hf0.78Y0.2 bulk metallic glasses (Zr-BMGs) were systematically investigated. Increasing tungsten content enhanced the mechanical strength of SWF/Zr-BMGCs from 1543 MPa to 1984 MPa by inhibiting propagation of shear bands, and ballistic gun tests demonstrated that tungsten fibers significantly improved the penetration capability of SWF/BMGC fragments. However, analysis of binarized images and quasi-closed chamber overpressure data indicated that the flare area and peak overpressure are reduced at the same impact velocity of 1000 m/s, reflecting a lower energy density per unit mass and reaction efficiency of 435.5 J/g and 4.14 % for SWF/Zr-BMGCs compared to 1592.1 J/g and 15.12 % of Zr-BMGs. This primarily results from the reduced exposed oxidation area during impact due to larger fragmented sizes and interfacial adhesion effects. In addition, the active elements Zr, Al, and Ni could burn preferentially under impact, which in turn contributes to the oxidation of elements Cu and W with high melting points. This work could improve the understanding of energy-release behavior of ex-situ second-phase reinforced Zr-BMGs under impact and support their further application.

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动态载荷下钨含量对短钨纤维/Zr-BMGCs力学性能、点火和能量释放特性的影响
采用熔融渗铸法制备了短钨纤维/ zr基大块金属玻璃复合材料(SWF/ zr - bmgc)。系统研究了钨含量对Zr59.62Cu14.4Ni12Al10Nb3Hf0.78Y0.2大块金属玻璃(zr - bmg)力学性能和动态载荷下能量释放特性的影响。增加钨含量可以抑制剪切带的传播,使SWF/ zr -BMGC破片的机械强度从1543 MPa提高到1984 MPa,弹道炮试验表明,钨纤维显著提高了SWF/BMGC破片的侵彻能力。然而,对二值化图像和准封闭腔室超压数据的分析表明,在相同的冲击速度为1000 m/s时,耀斑面积和峰值超压减小,反映出SWF/Zr-BMGCs的单位质量能量密度和反应效率分别为435.5 J/g和4.14%,而Zr-BMGCs的反应效率为1592.1 J/g和15.12%。这主要是由于在撞击过程中由于较大的碎片尺寸和界面粘附效应而减少了暴露的氧化区域。此外,Zr、Al和Ni等活性元素在冲击下优先燃烧,从而导致高熔点元素Cu和W的氧化。该研究有助于提高对非原位第二相增强zr - bmg在冲击作用下能量释放行为的认识,并为其进一步应用提供支持。
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来源期刊
Materials & Design
Materials & Design Engineering-Mechanical Engineering
CiteScore
14.30
自引率
7.10%
发文量
1028
审稿时长
85 days
期刊介绍: Materials and Design is a multi-disciplinary journal that publishes original research reports, review articles, and express communications. The journal focuses on studying the structure and properties of inorganic and organic materials, advancements in synthesis, processing, characterization, and testing, the design of materials and engineering systems, and their applications in technology. It aims to bring together various aspects of materials science, engineering, physics, and chemistry. The journal explores themes ranging from materials to design and aims to reveal the connections between natural and artificial materials, as well as experiment and modeling. Manuscripts submitted to Materials and Design should contain elements of discovery and surprise, as they often contribute new insights into the architecture and function of matter.
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