Parametric optimization of aloe vera coagulant for nitrate removal from textile wastewater using response surface methodology (RSM)

IF 4.2 Q2 CHEMISTRY, MULTIDISCIPLINARY Results in Chemistry Pub Date : 2025-02-09 DOI:10.1016/j.rechem.2025.102111
Lukman Shehu Mustapha , Kehinde Shola Obayomi
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Abstract

Textile production wastewater's composition has been an issue since it contains organic material and inorganic pollutants, making treatment difficult. This study used aloe vera as a natural coagulant to remediate wastewater. This objective was to use response surface methods to optimize operating parameters on the removal efficiency of nitrate removal through the application of response surface methodology (RSM). The influence of four factors such as aloe vera dosage, agitation time, agitation speed, and settling time on the removal of nitrate was examined to determine the optimal conditions for water treatment. The selected range of operating parameters is 20–40 min agitation time, 60–120 min settling time, a dosage of 0.5–1.5 g/L, and an agitation speed of 150–250 rpm respectively. Validation was carried out on the acquired data using the quadratic model. The optimal conditions for achieving the highest nitrate removal were determined as follows: 20 min agitation time, settling time of 120 min, 0.5 g/L dosage of aloe vera and 150 rpm agitation speed. The established conditions were confirmed through replication, resulting in 97% removal of nitrate. Functionalized groups that cause coagulation were revealed by Fourier-transform infrared spectroscopy (FTIR) and a firm, dense structure shown by scanning electron microscopy analysis suggested that contaminants had adhered to the coagulant. The findings of this research have potential practical applications on an industrial scale for water treatment purposes.

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响应面法优化芦荟絮凝剂去除纺织废水硝酸盐的参数
纺织生产废水的组成一直是一个问题,因为它含有有机物质和无机污染物,使处理困难。本研究采用芦荟作为天然混凝剂对废水进行修复。目的是利用响应面法,通过响应面法(RSM)优化操作参数对硝酸盐去除效率的影响。考察了芦荟用量、搅拌时间、搅拌速度、沉淀时间等4个因素对水中硝酸盐去除率的影响,确定了水处理的最佳条件。选择的运行参数范围分别为搅拌时间20 ~ 40 min,沉淀时间60 ~ 120 min,投加量0.5 ~ 1.5 g/L,搅拌转速150 ~ 250 rpm。利用二次元模型对采集的数据进行验证。确定了最高硝酸盐去除率的最佳条件为:搅拌时间20 min,沉淀时间120 min,芦荟用量0.5 g/L,搅拌速度150 rpm。通过复制验证了所建立的条件,硝酸盐去除率达到97%。傅里叶变换红外光谱(FTIR)发现了导致凝血的官能团,扫描电镜分析显示了坚固致密的结构,表明污染物已经粘附在凝血剂上。本研究结果在水处理工业规模上具有潜在的实际应用价值。
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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