Experimental study on ZDDP tribofilm formation in grease lubricated rolling/sliding contacts

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2025-06-01 Epub Date: 2025-02-09 DOI:10.1016/j.triboint.2025.110594
Rui Yu , Haichao Liu , Qingmiao Sun , Wenjing Lou , Shengmao Zhang , Xiaobo Wang , Yan Zhao
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Abstract

The tribofilm formation mechanisms of Zinc dialkyldithiophosphate (ZDDP) anti-wear additives have been extensively studied in oil lubrication. However, they are rarely reported in grease lubrication. In this study, the Mini Traction Machine (MTM) equipped with the Spacer Layer Interferometry iMaging (SLIM) technique is used to monitor the formation of ZDDP tribofilms in situ in Lithium-based grease- and its corresponding base oil- and bled oil- lubricated rolling/sliding contacts at low speeds. The results indicate that, compared to oil lubrication, the thickener deposited films hinder the formation of ZDDP tribofilms through reducing the interfacial friction in grease lubrication under moderate lubrication conditions. Among various operating conditions and ZDDP concentrations, the slide-to-roll ratio (SRR) dominates the formation of the ZDDP tribofilms by removing the grease thickener deposited films. By further extending to severe operating conditions in terms of load, temperature, SRR, and ZDDP concentration, the growing process of tribofilms have been analyzed for low-speed grease lubrication.
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油脂润滑的滚动/滑动触头中 ZDDP 三膜形成的实验研究
二烷基二硫代磷酸锌(ZDDP)抗磨添加剂的摩擦膜形成机理在润滑油润滑中得到了广泛的研究。然而,它们很少在油脂润滑中被报道。在这项研究中,配备间隔层干涉成像(SLIM)技术的微型牵引机(MTM)用于监测锂基润滑脂及其相应的基础油和低速滚动/滑动触点中ZDDP摩擦膜的原位形成。结果表明,与油润滑相比,在中等润滑条件下,增稠剂沉积膜通过降低润滑脂润滑时的界面摩擦,阻碍了ZDDP摩擦膜的形成。在不同的操作条件和ZDDP浓度下,滑滚比(SRR)通过去除润滑脂增稠剂沉积膜而主导ZDDP摩擦膜的形成。通过进一步扩展到载荷、温度、SRR和ZDDP浓度等恶劣工况,分析了低速润滑脂润滑摩擦膜的生长过程。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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