Enhancing heavy crude oil mobility at reservoir conditions by nanofluid injection in wells with previous steam stimulation cycles: Experimental evaluation and field trial implementation

IF 5.2 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Liquids Pub Date : 2025-04-15 Epub Date: 2025-02-03 DOI:10.1016/j.molliq.2025.127024
Carlos A. Franco , Oscar E. Medina , Dahiana Galeano-Caro , Lina M. Salinas , Luis G. Alzate , Daniela Molina , Gabriel J. Rendón , Cristian C. Obregón , Sergio H. Lopera , Farid B. Cortes , Camilo A. Franco
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Abstract

This study introduced a novel nanofluid injection method to enhance heavy crude oil recovery in steam-impacted wells, offering an alternative to traditional steam injection techniques. This research focuses on improving oil mobility by disrupting the viscoelastic network of asphaltenes through silica nanoparticle adsorption. Comprehensive experimental evaluations included nanoparticle characterization, reservoir fluid analysis, and dynamic core-flooding tests under reservoir conditions. Three carrier fluids, surfactant-based (SB), diesel-based (DT), and light hydrocarbon with surfactant (LHC + S), were tested with silica nanoparticles to identify the most effective combination. Key findings demonstrated that a concentration of 300 mg L−1 of silica nanoparticles dispersed in LHC + S reduced oil viscosity by 57 % at 25 °C, lowered the contact angle from 47° to 15°, and decreased interfacial tension by 38.0 %. Core flooding revealed that nanofluid injection increased the recovery factor from 89 % to 92 %, confirming enhanced crude oil displacement. Field trials in two mature wells subjected to four prior steam cycles showed oil production increases of 32 % and 56 % during the first-month post-treatment, with cumulative gains of 11,148 Bbl and 2240 Bbl, respectively. Additionally, viscosity reductions of 60 % were sustained over 12 months, validating the long-term efficacy of nanofluid injection as a nonthermal Enhanced Oil Recovery (EOR) method. By eliminating the need for steam and significantly improving the oil displacement efficiency, this study demonstrates the potential of nanofluid injection to reduce the operational costs and environmental impact in heavy oil fields undergoing thermal depletion.

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通过注入纳米流体提高稠油在油藏条件下的流动性:实验评估和现场试验实施
该研究介绍了一种新的纳米流体注入方法,以提高蒸汽冲击井的重质原油采收率,为传统的注汽技术提供了一种替代方案。这项研究的重点是通过纳米二氧化硅吸附破坏沥青质的粘弹性网络来改善油的流动性。综合实验评估包括纳米颗粒表征、储层流体分析和储层条件下的动态岩心驱油测试。研究人员用二氧化硅纳米颗粒测试了三种载液,即表面活性剂基(SB)、柴油基(DT)和轻烃-表面活性剂(LHC + S),以确定最有效的组合。关键研究结果表明,在25℃时,分散在LHC + S中的二氧化硅纳米颗粒浓度为300 mg L−1时,油粘度降低57%,接触角从47°降低到15°,界面张力降低38.0%。岩心驱油表明,注入纳米流体将采收率从89%提高到92%,证实了原油驱替能力的提高。经过4次蒸汽循环的两口成熟井的现场试验表明,在处理后的第一个月,原油产量分别增加了32%和56%,累计产量分别为11148桶和2240桶。此外,在12个月的时间里,粘度降低了60%,验证了纳米流体注入作为一种非热提高采收率(EOR)方法的长期有效性。通过消除对蒸汽的需求并显著提高驱油效率,该研究证明了纳米流体注入在稠油热枯竭油田降低作业成本和环境影响方面的潜力。
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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