Stepwise Diffusion Characteristics in Coal Mass under In Situ High-Stress Conditions

IF 5.2 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-02-04 DOI:10.1021/acs.energyfuels.4c0581010.1021/acs.energyfuels.4c05810
Tingting Zhao, Zhengdong Liu*, Xiaomin Hu, Wancheng Zhu, Shuyuan Liu, Leilei Si, Bao Qu, Chaojie Wang and Yihuai Zhang, 
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Abstract

The study of methane diffusion within coal is a critical theoretical foundation for coalbed methane extraction technologies. Currently, the development of coalbed methane resources is significantly constrained by the high-stress and low-permeability characteristics of deep coal seams. This necessitates an urgent focus on investigating the diffusion behavior of methane within the deep coal seams. This study investigates the stepwise diffusion characteristics of methane in coal under high-stress conditions. A series of experiments were carried out using a specially designed experimental apparatus aimed at this purpose to investigate the behavior of methane diffusion and to determine the dominant diffusion patterns in high-stress conditions. A diffusion model was constructed to calculate the diffusion coefficients of coal under high-stress conditions, which were then employed to perform numerical simulations of methane extraction based on the identified stepwise diffusion patterns. This analysis enabled the exploration of more economical and efficient methods of methane extraction. The results indicate that the adoption of a multistep diffusion pathway can effectively enhance methane desorption. When the diffusion pathways are uniform, the amount of desorption in the higher-level diffusion stage surpasses that in the lower-level diffusion stage. Additionally, the methane diffusion coefficient increases with a greater diffusion pressure gradient; however, simply increasing the diffusion pressure gradient does not necessarily lead to a significant increase in the desorption. Based on these findings, an intelligent extraction method was proposed, which enhances methane extraction efficiency while remaining economically viable and effective. The outcomes of this research provide theoretical support for understanding the mechanisms underlying methane extraction in high-stress coal seams.

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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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