Stepwise Diffusion Characteristics in Coal Mass under In Situ High-Stress Conditions

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-02-04 DOI:10.1021/acs.energyfuels.4c05810
Tingting Zhao, Zhengdong Liu*, Xiaomin Hu, Wancheng Zhu, Shuyuan Liu, Leilei Si, Bao Qu, Chaojie Wang and Yihuai Zhang, 
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Abstract

The study of methane diffusion within coal is a critical theoretical foundation for coalbed methane extraction technologies. Currently, the development of coalbed methane resources is significantly constrained by the high-stress and low-permeability characteristics of deep coal seams. This necessitates an urgent focus on investigating the diffusion behavior of methane within the deep coal seams. This study investigates the stepwise diffusion characteristics of methane in coal under high-stress conditions. A series of experiments were carried out using a specially designed experimental apparatus aimed at this purpose to investigate the behavior of methane diffusion and to determine the dominant diffusion patterns in high-stress conditions. A diffusion model was constructed to calculate the diffusion coefficients of coal under high-stress conditions, which were then employed to perform numerical simulations of methane extraction based on the identified stepwise diffusion patterns. This analysis enabled the exploration of more economical and efficient methods of methane extraction. The results indicate that the adoption of a multistep diffusion pathway can effectively enhance methane desorption. When the diffusion pathways are uniform, the amount of desorption in the higher-level diffusion stage surpasses that in the lower-level diffusion stage. Additionally, the methane diffusion coefficient increases with a greater diffusion pressure gradient; however, simply increasing the diffusion pressure gradient does not necessarily lead to a significant increase in the desorption. Based on these findings, an intelligent extraction method was proposed, which enhances methane extraction efficiency while remaining economically viable and effective. The outcomes of this research provide theoretical support for understanding the mechanisms underlying methane extraction in high-stress coal seams.

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原位高应力条件下煤体的逐步扩散特性
煤中甲烷扩散的研究是煤层气开采技术的重要理论基础。目前,深部煤层的高应力、低渗透特征严重制约着煤层气资源的开发。这就迫切需要对甲烷在深部煤层中的扩散行为进行研究。研究了高应力条件下煤中甲烷的逐步扩散特性。为此,利用专门设计的实验装置进行了一系列实验,研究了甲烷在高应力条件下的扩散行为,并确定了主要的扩散模式。建立了煤的扩散模型,计算了煤在高应力条件下的扩散系数,并基于所识别的逐步扩散模式对瓦斯抽采过程进行了数值模拟。这一分析有助于探索更经济、更有效的甲烷提取方法。结果表明,采用多步扩散途径可以有效地促进甲烷的解吸。当扩散路径均匀时,高阶扩散阶段的解吸量大于低阶扩散阶段。甲烷扩散系数随扩散压力梯度的增大而增大;然而,简单地增加扩散压力梯度并不一定会导致解吸的显著增加。在此基础上,提出了一种智能提取方法,在提高甲烷提取效率的同时保持经济上的可行性和有效性。研究结果为认识高应力煤层甲烷抽采机理提供了理论支持。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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