8-Hydroxyquinoline based novel fluorogenic sensor for Sensitive and selective Cd2+ detection and its Applications: Soil, Foodstuffs, smartphone and living cell

IF 4.7 3区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Photochemistry and Photobiology A-chemistry Pub Date : 2025-07-01 Epub Date: 2025-02-08 DOI:10.1016/j.jphotochem.2025.116336
Meliha Kutluca Alici
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Abstract

Cadmium is extensively utilized in various fields, mostly in industry and agriculture. Cadmium contamination of food, water, and soil can lead to major issues, like metabolic diseases and environmental degradation. The detection of cadmium is important due to these problems. In this study, an uncomplicated, efficient, and reversible fluorogenic sensor, HQM (2-amino-3-(((8-hydroxyquinolin-7-yl)methylene)amino)maleonitrile), composed of 7-formyl-8-hydroxyquinoline linked to diaminomalonitrile, was created for the determination of Cd2+. the sensor exhibited high selectivity for Cd2+ among various metal ions. The detection limit of HQM for Cd2+ was calculated as 0.25 µM. Application experiments on soil, foodstuffs, and living cells demonstrated the effective in-situ detection capabilities of HQM for Cd2+, indicating its promising potential for simple, rapid, and in-situ monitoring of Cd2+ in solutions.
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基于8-羟基喹啉的新型荧光传感器用于Cd2+的灵敏和选择性检测及其在土壤、食品、智能手机和活细胞中的应用
镉被广泛应用于各个领域,主要是工业和农业。镉污染食物、水和土壤会导致重大问题,如代谢疾病和环境退化。由于这些问题,镉的检测显得尤为重要。本研究建立了一种简单、高效、可逆的荧光传感器HQM(2-氨基-3-((8-羟基喹啉-7-基)亚甲基)氨基)马来腈),该传感器由7-甲酰基-8-羟基喹啉与二氨基甲腈连接而成,用于Cd2+的测定。该传感器在多种金属离子中对Cd2+具有较高的选择性。计算HQM对Cd2+的检出限为0.25µM。在土壤、食品和活细胞上的应用实验证明了HQM对Cd2+的有效原位检测能力,表明其在简单、快速、原位监测溶液中Cd2+方面具有广阔的潜力。
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来源期刊
CiteScore
7.90
自引率
7.00%
发文量
580
审稿时长
48 days
期刊介绍: JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds. All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor). The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.
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