Exploring ionised metal flux fraction in magnetron sputtering: Insights from laboratory and industrial applications

IF 6.1 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2025-02-06 DOI:10.1016/j.surfcoat.2025.131866
Peter Klein , Jaroslav Hnilica , Vjačeslav Sochora , Petr Vašina
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Abstract

Magnetron sputtering is one of the cornerstones of thin film-forming methods. The literature provides excessive knowledge about inner plasma processes, deposition control and thin film growth, but the overwhelming majority reports on results conducted on a small lab scale. To transfer this knowledge and use it in industrial applications, one has to overcome many challenges, the most profound being scaling the process from the lab scale towards a large industrial scale. This paper explores the critical differences in deposition fluxes and ionisation of metals when scaling from lab to industrial systems. While in the laboratory, the direct current magnetron sputtering does not create sufficient metal ions, this is dramatically different in the industrial system, where up to 30% of the film-forming species detected were ions. Additionally, the deposition rate in the industrial system was about one order of magnitude higher compared to the laboratory system.
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探索磁控溅射中的电离金属通量分数:来自实验室和工业应用的见解
磁控溅射是薄膜形成方法的基础之一。文献提供了过多的关于内部等离子体过程,沉积控制和薄膜生长的知识,但绝大多数报告的结果是在小实验室规模上进行的。为了转移这些知识并将其用于工业应用,人们必须克服许多挑战,其中最深刻的挑战是将该过程从实验室规模扩展到大规模工业规模。本文探讨了从实验室到工业系统缩放时金属的沉积通量和电离的关键差异。虽然在实验室中,直流磁控溅射不能产生足够的金属离子,但在工业系统中,这是截然不同的,在工业系统中,检测到的成膜物质中有多达30%是离子。此外,与实验室系统相比,工业系统中的沉积速率大约高一个数量级。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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