Revisiting semi-massive Sulfides: Textures of sulfide-silicate interactions in magmatic sulfide deposits

IF 3.6 2区 地球科学 Q1 GEOLOGY Ore Geology Reviews Pub Date : 2025-01-24 DOI:10.1016/j.oregeorev.2025.106457
Dominic Raisch, Sebastian Staude, Gregor Markl
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Abstract

The interaction of sulfide melt with silicate melt or partially molten country rock produces a wide variety of textures that can appear similar to net-textured sulfides which originate from accumulation of sulfide melt within the host intrusion and therefore occur in different areas within the orebody. This similarity in textures can cause misidentification during exploration and could cause confusion and wrong financial decisions. Therefore, these semi-massive sulfide textures were investigated in detail and partly redefined. They comprise (1) net, (2) infiltration, (3) disaggregation, and (4) emulsion textures.
Net-textured sulfides form by sulfide melt infiltrating into existing silicate cumulate thereby replacing interstitial silicate melt resulting in a continuous matrix of sulfides enclosing magmatic cumulate silicates. Silicates like pyroxenes display the highest XMg values of all textures and are occasionally sector-zoned. Contrary, infiltration, disaggregation and emulsion textures form by the infiltration of sulfide melt into the country rock by partial melting. Infiltration textures form during the initial process and are therefore defined by refractory fragments of country rock with abundant peritectic phases with additional minor amounts of anatectic melt enclosed in a continuous matrix of magmatic sulfides. Disaggregation textures represent the refractory end-stage and are defined as single grains or clusters of high thermal stability silicate crystals derived from the country rock suspended in magmatic sulfides. Macroscopically, this texture can look identical to net-textured sulfides, but can be distinguished by the lack of magmatic silicates, such as olivine, by elevated Ni and Mn contents plus lower XMg values of pyroxenes and by different luminescence colours of plagioclase in the disaggregation texture. The newly formed buoyant and immiscible silicate melt is less dense than the sulfide melt resulting in upward counter migration and the formation of the emulsion texture when frozen in. Depending on the ratio of the two melts, this texture may appear as a fine-grained droplet emulsion or as a connected bicontinuous emulsion, but both types have the same defining characteristics, such as high levels of eutectic intergrowths, newly formed skeletal and euhedral silicate crystals, and they contain high levels of hydrous silicates.
The newly crystallized pyroxenes in the emulsion texture exhibit the highest Ni and Mn contents and lowest XMg values compared to all other textures, and in addition, plagioclase again shows different luminescence colours. Where the newly formed silicate melt is trapped, it can form pegmatoidal pockets displaying the same features as the emulsion textures, but with less sulfides.

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重温半块状硫化物:岩浆硫化物矿床中硫化物-硅酸盐相互作用的结构
硫化物熔体与硅酸盐熔体或部分熔融的乡村岩石的相互作用产生了各种各样的结构,这些结构看起来类似于网状硫化物,它们起源于硫化物熔体在宿主侵入体内的积累,因此出现在矿体内的不同区域。这种纹理上的相似性可能会导致勘探过程中的错误识别,并可能导致混乱和错误的财务决策。因此,对这些半块状硫化物结构进行了详细的研究,并对其进行了部分重新定义。它们包括(1)网状结构,(2)渗透结构,(3)分解结构和(4)乳液结构。网状硫化物的形成是由硫化物熔体渗透到现有的硅酸盐堆积中,从而取代间隙的硅酸盐熔体,导致硫化物包围岩浆堆积硅酸盐的连续基质。像辉石这样的硅酸盐显示出所有结构中最高的XMg值,并且偶尔会出现扇形分区。相反,硫化物熔体部分熔融渗透到围岩中,形成浸润、崩解和乳状结构。渗透结构是在初始过程中形成的,因此由含有丰富包晶相的乡村岩石的难熔碎片和包裹在岩浆硫化物连续基质中的少量透晶熔体来定义。崩解结构代表了难熔末期,被定义为来自岩浆硫化物中悬浮的乡村岩石的高热稳定性硅酸盐晶体的单粒或簇状结构。宏观上看,这种结构看起来与网状结构的硫化物相同,但可以通过缺乏岩浆硅酸盐(如橄榄石)、高Ni和Mn含量加上较低的辉石XMg值以及在分解结构中斜长石的不同发光颜色来区分。新形成的浮力不混溶硅酸盐熔体比硫化物熔体密度小,导致向上反迁移,冻结时形成乳状织构。根据两种熔体的比例,这种结构可能表现为细粒滴状乳液或连接的双连续乳液,但这两种类型都具有相同的定义特征,例如高水平的共晶共生,新形成的骨架和自面体硅酸盐晶体,并且它们含有高水平的含水硅酸盐。乳化液织构中新结晶的辉石的Ni和Mn含量最高,XMg值最低,而且斜长石的发光颜色也不同。在新形成的硅酸盐熔体被捕获的地方,它可以形成与乳化液结构相同的花格状口袋,但硫化物较少。
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来源期刊
Ore Geology Reviews
Ore Geology Reviews 地学-地质学
CiteScore
6.50
自引率
27.30%
发文量
546
审稿时长
22.9 weeks
期刊介绍: Ore Geology Reviews aims to familiarize all earth scientists with recent advances in a number of interconnected disciplines related to the study of, and search for, ore deposits. The reviews range from brief to longer contributions, but the journal preferentially publishes manuscripts that fill the niche between the commonly shorter journal articles and the comprehensive book coverages, and thus has a special appeal to many authors and readers.
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