首页 > 最新文献

Ore Geology Reviews最新文献

英文 中文
Pegmatite evolution and mineralization: insights from tourmaline geochemistry and boron isotopes 伟晶岩演化与矿化:来自电气石地球化学和硼同位素的见解
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-04 DOI: 10.1016/j.oregeorev.2026.107156
Liu Xuemin , Wu Xu , Yang Yuanliang , Yue Dabin , Liao Xingjian , Zhao Pufeng , Wang Guozhi , Liu Bingli
While the magmatic source and evolution significantly influence rare metal mineralization in pegmatites, a critical unresolved question remains: within the same mining district, some spatially close pegmatites are mineralized while others are not. This highlights the existence of other crucial factors governing pegmatite mineralization. Tourmaline, a common borosilicate mineral in pegmatite systems, serves as a key indicator for deciphering mineralization processes. We studied the tourmaline from the Murong Li deposit (Asia’s largest single-vein Li deposit) using geochemistry, boron isotopes, and mineralogy. Three types were identified: BP-Tur (tourmaline in barren pegmatite), FP-Tur (tourmaline in fertile pegmatite), and AC-Tur (tourmaline in altered country rock). BP-Tur and FP-Tur exhibit pronounced zoning textures, indicating magmatic-hydrothermal formation. BP-Tur crystallized in a low-salinity, high-ƒO2, fluid-rich setting. In contrast, FP-Tur formed under initially low ƒO2 and low salinity, with both parameters increasing during later crystallization. AC-Tur is fine-grained, non-zoned and formed in a low-temperature, high-pressure, high-salinity, and high-ƒO2 environment. Its heavier δ11B values stem from 11B-enriched magmatic fluids. Systematic boron isotope variations across growth zones in BP-Tur and FP-Tur record magmatic evolution under open and closed conditions, respectively. This interpretation is corroborated by higher estimated pressures for FP-Tur relative to BP-Tur, consistent with fluid loss and pressure decrease in open systems. Unlike previous studies, we find no direct correlation between the contents of Li, Sn, Nb, or Ta in tourmaline and mineralization. Instead, the closure of the magmatic system is a critical control on Li mineralization.
岩浆来源和演化对伟晶岩中稀有金属的成矿作用具有重要影响,但在同一矿区内,一些空间上接近的伟晶岩被成矿,而另一些则没有成矿,这是一个尚未解决的关键问题。这突出了控制伟晶岩成矿的其他关键因素的存在。碧玺是伟晶岩系统中常见的硼硅酸盐矿物,是破译成矿过程的关键指标。利用地球化学、硼同位素和矿物学等方法对亚洲最大的单脉锂矿床——慕容里矿的电气石进行了研究。确定了3种类型:BP-Tur(裸露伟晶岩中的碧玺)、FP-Tur(肥沃伟晶岩中的碧玺)和AC-Tur(蚀变围岩中的碧玺)。BP-Tur和FP-Tur具有明显的分带结构,表明岩浆-热液形成。bp - turr在低盐度、高-ƒO2、富流体的环境中结晶。fp - turr在初始低ƒO2和低盐度条件下形成,在结晶后期这两个参数都增加。AC-Tur是在低温、高压、高盐度、高-ƒO2环境下形成的细粒、无分带。其较重的δ11B值源于富含11b的岩浆流体。BP-Tur和FP-Tur发育带间的系统硼同位素变化分别记录了开放和封闭条件下的岩浆演化过程。这一解释得到了fp - turr相对于bp - turr更高的估计压力的证实,这与开放式系统的流体漏失和压力下降相一致。与以往的研究不同,我们发现电气石中Li、Sn、Nb或Ta的含量与矿化之间没有直接的相关性。相反,岩浆体系的封闭性是控制锂矿化的关键因素。
{"title":"Pegmatite evolution and mineralization: insights from tourmaline geochemistry and boron isotopes","authors":"Liu Xuemin ,&nbsp;Wu Xu ,&nbsp;Yang Yuanliang ,&nbsp;Yue Dabin ,&nbsp;Liao Xingjian ,&nbsp;Zhao Pufeng ,&nbsp;Wang Guozhi ,&nbsp;Liu Bingli","doi":"10.1016/j.oregeorev.2026.107156","DOIUrl":"10.1016/j.oregeorev.2026.107156","url":null,"abstract":"<div><div>While the magmatic source and evolution significantly influence rare metal mineralization in pegmatites, a critical unresolved question remains: within the same mining district, some spatially close pegmatites are mineralized while others are not. This highlights the existence of other crucial factors governing pegmatite mineralization. Tourmaline, a common borosilicate mineral in pegmatite systems, serves as a key indicator for deciphering mineralization processes. We studied the tourmaline from the Murong Li deposit (Asia’s largest single-vein Li deposit) using geochemistry, boron isotopes, and mineralogy. Three types were identified: BP-Tur (tourmaline in barren pegmatite), FP-Tur (tourmaline in fertile pegmatite), and AC-Tur (tourmaline in altered country rock). BP-Tur and FP-Tur exhibit pronounced zoning textures, indicating magmatic-hydrothermal formation. BP-Tur crystallized in a low-salinity, high-ƒO<sub>2</sub>, fluid-rich setting. In contrast, FP-Tur formed under initially low ƒO<sub>2</sub> and low salinity, with both parameters increasing during later crystallization. AC-Tur is fine-grained, non-zoned and formed in a low-temperature, high-pressure, high-salinity, and high-ƒO<sub>2</sub> environment. Its heavier δ<sup>11</sup>B values stem from <sup>11</sup>B-enriched magmatic fluids. Systematic boron isotope variations across growth zones in BP-Tur and FP-Tur record magmatic evolution under open and closed conditions, respectively. This interpretation is corroborated by higher estimated pressures for FP-Tur relative to BP-Tur, consistent with fluid loss and pressure decrease in open systems. Unlike previous studies, we find no direct correlation between the contents of Li, Sn, Nb, or Ta in tourmaline and mineralization. Instead, the closure of the magmatic system is a critical control on Li mineralization.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107156"},"PeriodicalIF":3.6,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ trace element and sulfur isotope characteristics of pyrite from the Dapingzhang Cu − Au polymetallic deposit: Insights into Au mineralization processes 大坪章铜金多金属矿床黄铁矿原位微量元素及硫同位素特征:对金成矿过程的启示
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-03 DOI: 10.1016/j.oregeorev.2026.107154
Shanshan Ru , Guo Li , Chuandong Xue , Feng Li
The Dapingzhang Cu − Au polymetallic deposit is a large volcanogenic massive sulfide (VMS) deposit formed during the Proto − Tethyan stage in western Yunnan Province, SW China, and exhibits a stratified distribution with upper massive orebodies (V1) and lower veinlet orebodies (V2). Au − rich orebodies predominantly occur within the massive orebodies near the 16# exploration line. This study investigates the microstructures, trace elemental, and sulfur isotopic compositions of pyrite, chalcopyrite, and sphalerite from the Au − rich orebodies at 1150 m and 1130 m levels to constrain the Au-bearing hydrothermal fluid sources, migration, and ore genesis. Four pyrite types were identified, representing three mineralization stages: (1) early-stage Py1 − 1 with sedimentary-formed strawberry − like textures; (2) late-stage Py1 − 2 formed through Py1 − 1 aggregation into irregular or euhedral crystals; and (3) Py2 (first-order zoning on Py1 − 2) and Py3 (second-order zoning on Py2). All Py1 − 2, Py2, and Py3 are hydrothermal in origin. Trace elemental composition reveals higher Sb concentrations in pyrite at the 1150 m level compared to those at the 1130 m level, with similar concentrating trends of Cu, Pb, Au, and Se. Evolutionary sequence analysis shows increasing Cu and Au concentrations but decreasing Co and Se concentrations in Py1 − 2, Py2, and Py3 across both the 1150 m and 1130 m levels. All pyrites are enriched in Au, Cu, Pb, Zn, and Sb but are depleted in Co, Ni, Tl, Se, Ti, and Sn. Sulfur isotope values (δ34S =  − 2.63 to + 1.12‰) of pyrite, chalcopyrite, and sphalerite suggest a magmatic sulfur affinity. Gold mineralization is associated with E − W-trending ore-conducting faults. Au − rich fluids migrated upward through fractures, leaching Py1 − 1 to form inclusion textures and causing localized recrystallization that produced Au − enriched Py1 − 2. Continuous fluid replenishment generated Au − rich Py2. Since Py2 − forming fluids were not fully consumed, Py3 − forming fluids added more Au, reaching supersaturation and precipitating native gold and calaverite within Py2 − Py3 intergrowths and fractures. Sustained fluid supply ultimately formed the Au − rich orebodies.
大坪章铜金多金属矿床是滇西原特提斯期形成的大型火山成因块状硫化物矿床,呈上块状矿体(V1)下脉状矿体(V2)层状分布。富金矿体主要产于16#探矿线附近块状矿体内。本文研究了1150 m和1130 m富金矿体中黄铁矿、黄铜矿和闪锌矿的微观结构、微量元素和硫同位素组成,以约束含金热液的来源、运移和矿床成因。鉴定出4种黄铁矿类型,分别代表3个成矿阶段:(1)早期Py1−1期,具有沉积形成的草莓状结构;(2)晚期Py1−2通过Py1−1聚集形成不规则或自面体晶体;Py2 (Py1−2上的一级分区)和Py3 (Py2上的二级分区)。Py1−2、Py2和Py3均为热液成因。微量元素组成表明,1150 m水平黄铁矿中Sb含量高于1130 m水平,Cu、Pb、Au和Se富集趋势相似。演化序列分析表明,在1150 m和1130 m水平上,Py1−2、Py2和Py3中Cu和Au浓度升高,Co和Se浓度降低。所有黄铁矿均富集Au、Cu、Pb、Zn和Sb,而富集Co、Ni、Tl、Se、Ti和Sn。黄铁矿、黄铜矿和闪锌矿的硫同位素值(δ34S =−2.63 ~ + 1.12‰)表明它们具有岩浆硫亲和作用。金矿化与E - w向导矿断裂有关。富金流体通过裂缝向上运移,浸出Py1−1形成包裹体,局部再结晶生成富金Py1−2。连续补充流体生成富Au−Py2。由于形成Py2−的流体消耗不完全,形成Py3−的流体添加了更多的金,达到过饱和状态,在Py2−Py3共生体和裂缝中析出天然金和钙钙石。持续的流体供给最终形成了富金矿体。
{"title":"In situ trace element and sulfur isotope characteristics of pyrite from the Dapingzhang Cu − Au polymetallic deposit: Insights into Au mineralization processes","authors":"Shanshan Ru ,&nbsp;Guo Li ,&nbsp;Chuandong Xue ,&nbsp;Feng Li","doi":"10.1016/j.oregeorev.2026.107154","DOIUrl":"10.1016/j.oregeorev.2026.107154","url":null,"abstract":"<div><div>The Dapingzhang Cu − Au polymetallic deposit is a large volcanogenic massive sulfide (VMS) deposit formed during the Proto − Tethyan stage in western Yunnan Province, SW China, and exhibits a stratified distribution with upper massive orebodies (V1) and lower veinlet orebodies (V2). Au − rich orebodies predominantly occur within the massive orebodies near the 16<sup>#</sup> exploration line. This study investigates the microstructures, trace elemental, and sulfur isotopic compositions of pyrite, chalcopyrite, and sphalerite from the Au − rich orebodies at 1150 m and 1130 m levels to constrain the Au-bearing hydrothermal fluid sources, migration, and ore genesis. Four pyrite types were identified, representing three mineralization stages: (1) early-stage Py1 − 1 with sedimentary-formed strawberry − like textures; (2) late-stage Py1 − 2 formed through Py1 − 1 aggregation into irregular or euhedral crystals; and (3) Py2 (first-order zoning on Py1 − 2) and Py3 (second-order zoning on Py2). All Py1 − 2, Py2, and Py3 are hydrothermal in origin. Trace elemental composition reveals higher Sb concentrations in pyrite at the 1150 m level compared to those at the 1130 m level, with similar concentrating trends of Cu, Pb, Au, and Se. Evolutionary sequence analysis shows increasing Cu and Au concentrations but decreasing Co and Se concentrations in Py1 − 2, Py2, and Py3 across both the 1150 m and 1130 m levels. All pyrites are enriched in Au, Cu, Pb, Zn, and Sb but are depleted in Co, Ni, Tl, Se, Ti, and Sn. Sulfur isotope values (δ<sup>34</sup>S =  − 2.63 to + 1.12‰) of pyrite, chalcopyrite, and sphalerite suggest a magmatic sulfur affinity. Gold mineralization is associated with E − W-trending ore-conducting faults. Au − rich fluids migrated upward through fractures, leaching Py1 − 1 to form inclusion textures and causing localized recrystallization that produced Au − enriched Py1 − 2. Continuous fluid replenishment generated Au − rich Py2. Since Py2 − forming fluids were not fully consumed, Py3 − forming fluids added more Au, reaching supersaturation and precipitating native gold and calaverite within Py2 − Py3 intergrowths and fractures. Sustained fluid supply ultimately formed the Au − rich orebodies.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107154"},"PeriodicalIF":3.6,"publicationDate":"2026-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(U-Th)/He thermochronology constraints on Cenozoic exhumation of Ke’eryin lithium ore field, eastern Tibet (U-Th)/He热年代学对藏东柯尔音锂矿田新生代发掘的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107133
Jingbo Sun , Wen Chen , Kezhang Qin , Shuangfeng Zhao , Ze Shen , Bin Zhang , Wen Zhang
The Ke’eryin lithium ore field, located in the east of Songpan-Ganzi orogenic belt of Tibetan Plateau, is an important lithium-producing field hosting multiple pegmatite deposits in large to super-large scale. A more complete exhumation history of this ore field is required, and favorable prospecting locations need further identification. Here, we applied (U-Th)/He dating combined with a vertical profile sampling strategy to quantitatively constrain the exhumation process of the Ke’eryin lithium ore field. Zircon (U-Th)/He (ZHe) data and thermal history modeling reveal fast cooling during ∼28–24 Ma, linked to crustal shortening during the India-Eurasia collision. This phase removed ∼3.3 km of overburden, reducing burial depths from ∼5.3 km to ∼2 km. Age-elevation relationships of apatite (U-Th)/He (AHe) combined with thermal history modeling reveal rapid cooling at ∼15 Ma. This rapid cooling episode resulted from the regional uplift and exhumation, with amplification by river incision. The hanging wall (north) experienced greater denudation than the footwall (south), making the footwall a more favorable prospecting area. Combining the zircon and apatite (U-Th)/He data, we calculate a total erosion amount of approximately ∼5 km in the Ke’eryin lithium ore field since the Late Oligocene.
柯尔银锂矿田位于青藏高原松潘—甘孜造山带东段,是我国重要的大型至超大型多伟晶岩矿床产锂田。需要对该矿田进行更完整的发掘历史,并进一步确定有利的找矿位置。本文采用(U-Th)/He定年法结合垂直剖面采样策略,对柯尔银锂矿田的发掘过程进行了定量约束。锆石(U-Th)/He(喆)数据和热历史模拟显示,在~ 28-24 Ma期间,印度-欧亚大陆碰撞期间地壳缩短,导致了快速冷却。这一阶段移除了约3.3公里的覆盖层,将掩埋深度从约5.3公里减少到约2公里。结合热历史模型,磷灰石(U-Th)/He (AHe)的年龄-海拔关系显示在~ 15 Ma时快速冷却。这一快速降温事件是由区域隆升和挖掘引起的,并有河流切割的放大作用。上盘(北)的剥蚀程度大于下盘(南),下盘为有利找矿区。结合锆石和磷灰石(U-Th)/He数据,计算了晚渐新世以来柯二阴锂矿田的总侵蚀量约为~ 5 km。
{"title":"(U-Th)/He thermochronology constraints on Cenozoic exhumation of Ke’eryin lithium ore field, eastern Tibet","authors":"Jingbo Sun ,&nbsp;Wen Chen ,&nbsp;Kezhang Qin ,&nbsp;Shuangfeng Zhao ,&nbsp;Ze Shen ,&nbsp;Bin Zhang ,&nbsp;Wen Zhang","doi":"10.1016/j.oregeorev.2026.107133","DOIUrl":"10.1016/j.oregeorev.2026.107133","url":null,"abstract":"<div><div>The Ke’eryin lithium ore field, located in the east of Songpan-Ganzi orogenic belt of Tibetan Plateau, is an important lithium-producing field hosting multiple pegmatite deposits in large to super-large scale. A more complete exhumation history of this ore field is required, and favorable prospecting locations need further identification. Here, we applied (U-Th)/He dating combined with a vertical profile sampling strategy to quantitatively constrain the exhumation process of the Ke’eryin lithium ore field. Zircon (U-Th)/He (ZHe) data and thermal history modeling reveal fast cooling during ∼28–24 Ma, linked to crustal shortening during the India-Eurasia collision. This phase removed ∼3.3 km of overburden, reducing burial depths from ∼5.3 km to ∼2 km. Age-elevation relationships of apatite (U-Th)/He (AHe) combined with thermal history modeling reveal rapid cooling at ∼15 Ma. This rapid cooling episode resulted from the regional uplift and exhumation, with amplification by river incision. The hanging wall (north) experienced greater denudation than the footwall (south), making the footwall a more favorable prospecting area. Combining the zircon and apatite (U-Th)/He data, we calculate a total erosion amount of approximately ∼5 km in the Ke’eryin lithium ore field since the Late Oligocene.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107133"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mg isotopes and TIMA tracing the mantle source and mineralization process at Bayan Obo Nb-REE-Fe deposit, China 白云鄂博铌稀土铁矿床地幔源及成矿过程的Mg同位素和TIMA示踪
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107127
Qingyan Tang , Zhuoming Li , Chi Zhao , Yan Zhang , Hailong Jin , Biao Chen , Yanjiang Liu , Tianyu Qin , Tengda Yang , Min Qiao , Xinrui Bai , Zeyu Ma
The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ26Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ26Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ26Mg value of −0.19 ‰, while limestones display the lowest δ26Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ26Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ26Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.
碳酸盐岩地幔源中是否存在碳酸盐物质一直是人们争论的焦点。利用TIMA和Mg同位素揭示了碳酸盐岩和白云鄂博铌稀土铁矿床的成因。白云岩碳酸岩岩脉的δ26Mg值较正常地幔的δ26Mg值轻,范围为- 0.83‰~ - 0.43‰。粗粒白云岩碳酸盐(- 0.71‰~ - 0.03‰)和Nb-REE-Fe矿石的δ26Mg值变化明显,其中Nb-REE-Fe矿石的δ26Mg值变化范围较广,为- 0.72‰~ +0.31‰。灰岩的δ26Mg值为- 0.19‰,灰岩δ26Mg值最低,范围在- 1.88‰~ - 1.86‰之间。研究表明,白云鄂博碳酸岩起源于碳酸化橄榄岩的低程度部分熔融作用。古碳酸盐物质通过脱碳作用进入地幔源区。全岩δ26Mg值受多个矿物相控制,而非单一矿物相。地幔源、岩浆分异过程及后续热液交代作用共同影响了白云鄂博地区镁同位素组成。低于地幔值的δ26Mg值可能是由富含轻Mg同位素的矿物形成的。因此,古碳酸盐岩还涉及碳酸盐物质的添加。元素对比表明,酸性条件有利于Nb和REE的迁移富集,而碱性条件有利于REE的迁移富集,不利于Nb的迁移。
{"title":"Mg isotopes and TIMA tracing the mantle source and mineralization process at Bayan Obo Nb-REE-Fe deposit, China","authors":"Qingyan Tang ,&nbsp;Zhuoming Li ,&nbsp;Chi Zhao ,&nbsp;Yan Zhang ,&nbsp;Hailong Jin ,&nbsp;Biao Chen ,&nbsp;Yanjiang Liu ,&nbsp;Tianyu Qin ,&nbsp;Tengda Yang ,&nbsp;Min Qiao ,&nbsp;Xinrui Bai ,&nbsp;Zeyu Ma","doi":"10.1016/j.oregeorev.2026.107127","DOIUrl":"10.1016/j.oregeorev.2026.107127","url":null,"abstract":"<div><div>The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ<sup>26</sup>Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ<sup>26</sup>Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ<sup>26</sup>Mg value of −0.19 ‰, while limestones display the lowest δ<sup>26</sup>Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ<sup>26</sup>Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ<sup>26</sup>Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107127"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Genesis of ankerite and its relationship with uranium mineralization in the Hailijin uranium deposit, southern Songliao Basin, China 松辽盆地南部海里金铀矿床铁白云岩成因及其与铀矿化的关系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107130
Xin Hu , Hui Rong , Shihu Kang , Jun Ning , Guolong Tang , Liangliang Zhang , Shusong Ma
Ankerite cements in the Hailijin uranium deposit of the southern Songliao Basin serve as an excellent carrier for uranium mineralization. This study aims to characterize the morphology, contents, fluid inclusions, and elemental-isotopic compositions of the ankerite cements within the uranium reservoirs, and then reveals genesis of the ankerite and its relationship with uranium mineralization. In red sandstone, the ankerite is predominantly euhedral granular with an average content of 0.92 %. In yellow sandstone, it occurs as euhedral to subhedral crystals (average content: 0.62 %). In gray-white barren sandstone, it is mainly colloidal or granular, with an average content of 0.97 %. In mineralized sandstone, the ankerite exists in colloidal or granular form and has the highest average content (1.61 %). In primary gray sandstone, it appears as euhedral to subhedral crystals (average content: 0.94 %). Fluid inclusions in the ankerite yield homogenization temperatures of 140–180 °C (Th) and salinities of 8–12 wt% NaCl equiv. Sc, V, U, Zn, and Y exhibit remarkable enrichment in the ankerite, while Li, Cu, Rb, Ga, Zr, Nb, Ba, and Hf display systematic depletion patterns. The rare earth elements of ankerite generally exhibit the characteristics of light rare earth element depletion and heavy rare earth element enrichment. Ce/La ranges from 1.3 to 2.645, with an average value of 1.816, and Eu anomaly value (δEu) fluctuates between 0.881 and 1.093, with an average of 1.014. 87Sr/86Sr values of the ankerite range from 0.70598 to 0.70779, with an average value of 0.70748. The study indicates that the ankerite likely forms in hydrothermal fluids associated with basic dike intrusion. As temperature decreases, the ankerite and uranium minerals sequentially precipitate from these hydrothermal fluids. This study reveals the mechanism of hydrothermal fluids participating in mineralization of sandstone-hosted uranium deposits.
松辽盆地南部海里金铀矿床的铁白云石胶结物是铀矿化的优良载体。通过对铀矿储层中铁白云石胶结物的形态、含量、流体包裹体和元素同位素组成的表征,揭示铁白云石的成因及其与铀矿化的关系。红砂岩中,铁白云石以自面体颗粒为主,平均含量为0.92%。在黄色砂岩中以自面体至亚面体晶体存在(平均含量0.62%)。灰白色秃砂岩以胶体或粒状为主,平均含量为0.97%。在矿化砂岩中,铁白云石以胶体或粒状存在,平均含量最高(1.61%)。在原生灰色砂岩中,呈自面体至亚面体结晶,平均含量为0.94%。铁白云石中的流体包裹体均质温度为140 ~ 180℃(Th),盐度为8 ~ 12 wt% NaCl, Sc、V、U、Zn和Y在铁白云石中表现出显著富集,而Li、Cu、Rb、Ga、Zr、Nb、Ba和Hf表现出系统的亏缺模式。安吉矿稀土元素总体上表现出轻稀土元素贫、重稀土元素富集的特征。Ce/La变化范围为1.3 ~ 2.645,平均值为1.816;Eu异常值δEu变化范围为0.881 ~ 1.093,平均值为1.014。ankerite的87Sr/86Sr值在0.70598 ~ 0.70779之间,平均值为0.70748。研究表明,铁白云石可能形成于与基性岩脉侵入有关的热液流体中。随着温度的降低,铁白云石和铀矿物依次从这些热液中析出。研究揭示了热液流体参与砂岩型铀矿床成矿作用的机理。
{"title":"Genesis of ankerite and its relationship with uranium mineralization in the Hailijin uranium deposit, southern Songliao Basin, China","authors":"Xin Hu ,&nbsp;Hui Rong ,&nbsp;Shihu Kang ,&nbsp;Jun Ning ,&nbsp;Guolong Tang ,&nbsp;Liangliang Zhang ,&nbsp;Shusong Ma","doi":"10.1016/j.oregeorev.2026.107130","DOIUrl":"10.1016/j.oregeorev.2026.107130","url":null,"abstract":"<div><div>Ankerite cements in the Hailijin uranium deposit of the southern Songliao Basin serve as an excellent carrier for uranium mineralization. This study aims to characterize the morphology, contents, fluid inclusions, and elemental-isotopic compositions of the ankerite cements within the uranium reservoirs, and then reveals genesis of the ankerite and its relationship with uranium mineralization. In red sandstone, the ankerite is predominantly euhedral granular with an average content of 0.92 %. In yellow sandstone, it occurs as euhedral to subhedral crystals (average content: 0.62 %). In gray-white barren sandstone, it is mainly colloidal or granular, with an average content of 0.97 %. In mineralized sandstone, the ankerite exists in colloidal or granular form and has the highest average content (1.61 %). In primary gray sandstone, it appears as euhedral to subhedral crystals (average content: 0.94 %). Fluid inclusions in the ankerite yield homogenization temperatures of 140–180 °C (Th) and salinities of 8–12 wt% NaCl equiv. Sc, V, U, Zn, and Y exhibit remarkable enrichment in the ankerite, while Li, Cu, Rb, Ga, Zr, Nb, Ba, and Hf display systematic depletion patterns. The rare earth elements of ankerite generally exhibit the characteristics of light rare earth element depletion and heavy rare earth element enrichment. Ce/La ranges from 1.3 to 2.645, with an average value of 1.816, and Eu anomaly value (δEu) fluctuates between 0.881 and 1.093, with an average of 1.014. <sup>87</sup>Sr/<sup>86</sup>Sr values of the ankerite range from 0.70598 to 0.70779, with an average value of 0.70748. The study indicates that the ankerite likely forms in hydrothermal fluids associated with basic dike intrusion. As temperature decreases, the ankerite and uranium minerals sequentially precipitate from these hydrothermal fluids. This study reveals the mechanism of hydrothermal fluids participating in mineralization of sandstone-hosted uranium deposits.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107130"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Orogenic gold mineralization constrained by sphalerite geochemistry: evidence from the Bangbu deposit, Tibet, SW China 闪锌矿地球化学约束下的造山带金矿化——来自西藏邦布矿床的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107141
Xiangfa Song , Degao Zhai , Xiaolin Wang , Jinchao Wu , Zhi Zhang , Wei Chen , Zijun Qiu , Qingqing Zhao , Jiajun Liu
Located in the eastern segment of the Yarlung–Tsangpo suture zone (YTSZ), the Bangbu deposit formed during the subduction–collision evolution of the Himalayan–Tibetan orogen and constitutes a significant example of hydrothermal gold mineralization in this tectonic setting. Pyrite has commonly been employed to trace ore-forming processes in orogenic gold systems, but the role of coexisting sphalerite as an additional tracer mineral remains insufficiently investigated. This study presents a comprehensive geochemical characterization of sphalerite occurring with ore-stage pyrite in quartz–sulfide veins from the Bangbu deposit, and places these results in the context of a global dataset covering sphalerite from diverse mineralization environments. Compared with sphalerite from other deposit types, the Bangbu sphalerite is characterized by elevated Cd but depleted Ga, Mn and Sn. Both PLS-DA and its orthogonal variant (OPLS-DA) show that sphalerite from Bangbu represents a distinct geochemical cluster that is readily separable from typical magmatic–hydrothermal systems. Application of the GGIMFis geothermometer to the Bangbu sphalerite yields temperatures of 230–260 °C (peak at ∼250 °C), while the corresponding lgfS2 values of –14.5 to –12.4 point to intermediate- to low-sulfidation conditions. These parameters are consistent with medium to low temperature, low salinity, CO2-rich fluids and show no clear evidence for a significant magmatic or mantle-derived fluid component, and instead pointing to a predominantly metamorphic fluid origin. Coexisting sphalerite and pyrite display narrowly distributed δ34S values of ∼+2‰ and near-equilibrium isotopic fractionation, and their sulfur isotope compositions are lighter than those of sulfides in the surrounding low-grade metamorphic strata. This discrepancy with a simple metamorphic devolatilization model, together with the observation that δ34S values fall within the range expected for sulfur released by slab-derived fluids, supports a significant sub-crustal fluid contribution and indicates that a single metamorphic devolatilization model cannot fully explain the gold mineralization. Integrating constraints from trace element compositions, temperature estimates, sulfur fugacity and sulfur isotopes, this study proposes a two-stage genetic model for the Bangbu deposit, including subduction-related devolatilization pre-enrichment and metamorphic reactivation. The results demonstrate that ore-stage sphalerite provides independent constraints on the ore-forming conditions and fluid sources of orogenic gold deposits, and represents an important complement to traditional pyrite-based tracer systems.
邦布矿床位于雅鲁藏布缝合带(YTSZ)东段,形成于喜马拉雅—青藏造山带俯冲—碰撞演化过程中,是该构造背景下热液金矿化的重要例证。黄铁矿通常用于在造山带金系统中追踪成矿过程,但共存的闪锌矿作为另一种示踪矿物的作用仍未得到充分的研究。本研究对邦布矿床石英-硫化物脉中与矿级黄铁矿共生的闪锌矿进行了全面的地球化学表征,并将这些结果与覆盖不同成矿环境的闪锌矿全球数据集进行了对比。与其他矿床类型闪锌矿相比,邦布闪锌矿具有Cd升高、Ga、Mn、Sn亏缺的特点。PLS-DA及其正交方差(OPLS-DA)表明,邦布闪锌矿是一个独特的地球化学簇,易于与典型的岩浆-热液系统分离。GGIMFis地温计对邦布闪锌矿的测量温度为230-260°C(峰值为~ 250°C),而相应的lgfS2值为- 14.5至- 12.4,为中至低硫化条件。这些参数与中低温、低盐度、富co2流体一致,没有明确证据表明存在明显的岩浆或幔源流体成分,而是指向以变质流体为主的流体来源。闪锌矿与黄铁矿共生,δ34S值分布窄,δ34S值为~ +2‰,同位素分馏接近平衡,硫同位素组成轻于周围低品位变质地层硫化物。这与简单的变质脱挥发模型的差异,以及δ34S值落在板岩流体释放硫的预期范围内,支持了地壳下流体的重要贡献,表明单一的变质脱挥发模型不能完全解释金矿化。综合微量元素组成、温度估算、硫逸度和硫同位素等因素,提出了邦埠矿床俯冲脱挥发预富集和变质再活化两阶段成因模型。结果表明,矿级闪锌矿对造山带金矿成矿条件和流体来源具有独立的约束作用,是对传统黄铁矿示踪体系的重要补充。
{"title":"Orogenic gold mineralization constrained by sphalerite geochemistry: evidence from the Bangbu deposit, Tibet, SW China","authors":"Xiangfa Song ,&nbsp;Degao Zhai ,&nbsp;Xiaolin Wang ,&nbsp;Jinchao Wu ,&nbsp;Zhi Zhang ,&nbsp;Wei Chen ,&nbsp;Zijun Qiu ,&nbsp;Qingqing Zhao ,&nbsp;Jiajun Liu","doi":"10.1016/j.oregeorev.2026.107141","DOIUrl":"10.1016/j.oregeorev.2026.107141","url":null,"abstract":"<div><div>Located in the eastern segment of the Yarlung–Tsangpo suture zone (YTSZ), the Bangbu deposit formed during the subduction–collision evolution of the Himalayan–Tibetan orogen and constitutes a significant example of hydrothermal gold mineralization in this tectonic setting. Pyrite has commonly been employed to trace ore-forming processes in orogenic gold systems, but the role of coexisting sphalerite as an additional tracer mineral remains insufficiently investigated. This study presents a comprehensive geochemical characterization of sphalerite occurring with ore-stage pyrite in quartz–sulfide veins from the Bangbu deposit, and places these results in the context of a global dataset covering sphalerite from diverse mineralization environments. Compared with sphalerite from other deposit types, the Bangbu sphalerite is characterized by elevated Cd but depleted Ga, Mn and Sn. Both PLS-DA and its orthogonal variant (OPLS-DA) show that sphalerite from Bangbu represents a distinct geochemical cluster that is readily separable from typical magmatic–hydrothermal systems. Application of the GGIMFis geothermometer to the Bangbu sphalerite yields temperatures of 230–260 °C (peak at ∼250 °C), while the corresponding lg<em>f</em>S<sub>2</sub> values of –14.5 to –12.4 point to intermediate- to low-sulfidation conditions. These parameters are consistent with medium to low temperature, low salinity, CO<sub>2</sub>-rich fluids and show no clear evidence for a significant magmatic or mantle-derived fluid component, and instead pointing to a predominantly metamorphic fluid origin. Coexisting sphalerite and pyrite display narrowly distributed <em>δ</em><sup>34</sup>S values of ∼+2‰ and near-equilibrium isotopic fractionation, and their sulfur isotope compositions are lighter than those of sulfides in the surrounding low-grade metamorphic strata. This discrepancy with a simple metamorphic devolatilization model, together with the observation that <em>δ</em><sup>34</sup>S values fall within the range expected for sulfur released by slab-derived fluids, supports a significant sub-crustal fluid contribution and indicates that a single metamorphic devolatilization model cannot fully explain the gold mineralization. Integrating constraints from trace element compositions, temperature estimates, sulfur fugacity and sulfur isotopes, this study proposes a two-stage genetic model for the Bangbu deposit, including subduction-related devolatilization pre-enrichment and metamorphic reactivation. The results demonstrate that ore-stage sphalerite provides independent constraints on the ore-forming conditions and fluid sources of orogenic gold deposits, and represents an important complement to traditional pyrite-based tracer systems.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107141"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146079447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review of the relationship between highly fractionated intrusions and gold mineralization 高分异侵入体与金矿化关系研究进展
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107145
Qingxuan Wang , Shuo Wang , Zhengping Yan , Wenyuan Li , Yunhua Liu , Huali Guo , Jinhua Du , Yingxing Huang , Tianhong Gao , Zihe Chen
Highly fractionated intrusions plays a key role in the formation of numerous types of ore metal deposits. For example, many large-scale Au deposits are associated with highly fractionated intermediate–silicic intrusions. Since the introduction of Au deposit classification types such as intrusion-related, magmatic, and magmatic–hydrothermal Au deposits, an increasing number of studies have focused on the coupled relationships between magmatic processes (e.g., melt segregation, differentiation, and evolution) and Au mineralization. The magmatism not only provides the energy and ore-forming materials for Au mineralization, but also leads to significant Au enrichment by magmatic fractionation and evolution. Consequently, studies on magmatic fractionation-related mineralization should not be confined to ore types such as W–Sn and rare metals. This paper systematically reviews the nature of Au deposits genetically linked to highly fractionated magmas and discusses the key controls on anomalous Au enrichment during magmatic fractionation. The gold-mineralizing magmas are derived mainly from regions near the crust–mantle boundary. Metasomatic overprinting of the lithospheric mantle and enrichment of the lower crust by metallic elements, fluids, and volatiles from subducted slabs are preconditions for subsequent auriferous mineralization processes. The parental rocks of these Au deposits generally have a high O fugacity and are fractionated I-type or magnetite-series granites that have an affinity with the high-K calc-alkaline series, in which physicochemical parameters such as the O fugacity regulate the S speciation in the magmas and Au distribution. Furthermore, the timing of Au-bearing metallic sulfide saturation in the magmas and subsequent exsolution into the fluid phase is one of the critical controls on Au transportation into the shallow crust and its subsequent deposition in economically viable concentrations. Such Au deposits form mainly in transitional tectonic settings associated with slab subduction (e.g., slab rollback, break off) or during the transition from collisional to post-collisional tectonic settings. The physicochemical processes that govern melt segregation, differentiation, and Au enrichment from the magma source regions to final ore deposition have significant implications for understanding anomalous Au concentration mechanisms. The interrelationships among physicochemical parameters are the critical factor in understanding the coupling relationship between the melt-fluid evolution and Au mineralization, and therefore warrant further investigation.
高分异侵入体在多种类型矿床的形成中起着关键作用。例如,许多大型金矿床与高分馏中硅质侵入体有关。自侵入型、岩浆型、岩浆-热液型金矿床等金矿床分类类型被引入以来,越来越多的研究集中在岩浆过程(如熔体分离、分异和演化)与金矿化之间的耦合关系上。岩浆作用不仅为金矿化提供了能量和成矿物质,而且通过岩浆分馏和演化导致了显著的金富集。因此,岩浆分选成矿研究不应局限于钨锡、稀有金属等矿石类型。本文系统评述了与高分馏岩浆成因相关的金矿性质,讨论了岩浆分馏过程中异常金富集的关键控制因素。金矿化岩浆主要来源于地壳-地幔边界附近地区。岩石圈地幔的交代叠印和俯冲板块的金属元素、流体和挥发物对下地壳的富集是后续含金成矿作用的先决条件。这些金矿床的母岩一般具有较高的O逸度,为分选的i型或磁铁矿系列花岗岩,与高钾钙碱性系列有亲缘关系,其中O逸度等物化参数调节着岩浆中的S形态和Au的分布。此外,岩浆中含金金属硫化物的饱和和随后析出到流体相的时间是控制Au进入浅层地壳并随后以经济上可行的浓度沉积的关键因素之一。这类金矿主要形成于与板块俯冲(如板块回滚、断裂)相关的过渡性构造环境中,或形成于从碰撞构造环境到碰撞后构造环境的过渡时期。从岩浆源区到最终矿床,控制熔体偏析、分异和金富集的物理化学过程对理解异常金富集机制具有重要意义。物理化学参数之间的相互关系是理解熔融流体演化与金矿化耦合关系的关键因素,值得进一步研究。
{"title":"Review of the relationship between highly fractionated intrusions and gold mineralization","authors":"Qingxuan Wang ,&nbsp;Shuo Wang ,&nbsp;Zhengping Yan ,&nbsp;Wenyuan Li ,&nbsp;Yunhua Liu ,&nbsp;Huali Guo ,&nbsp;Jinhua Du ,&nbsp;Yingxing Huang ,&nbsp;Tianhong Gao ,&nbsp;Zihe Chen","doi":"10.1016/j.oregeorev.2026.107145","DOIUrl":"10.1016/j.oregeorev.2026.107145","url":null,"abstract":"<div><div>Highly fractionated intrusions plays a key role in the formation of numerous types of ore metal deposits. For example, many large-scale Au deposits are associated with highly fractionated intermediate–silicic intrusions. Since the introduction of Au deposit classification types such as intrusion-related, magmatic, and magmatic–hydrothermal Au deposits, an increasing number of studies have focused on the coupled relationships between magmatic processes (e.g., melt segregation, differentiation, and evolution) and Au mineralization. The magmatism not only provides the energy and ore-forming materials for Au mineralization, but also leads to significant Au enrichment by magmatic fractionation and evolution. Consequently, studies on magmatic fractionation-related mineralization should not be confined to ore types such as W–Sn and rare metals. This paper systematically reviews the nature of Au deposits genetically linked to highly fractionated magmas and discusses the key controls on anomalous Au enrichment during magmatic fractionation. The gold-mineralizing magmas are derived mainly from regions near the crust–mantle boundary. Metasomatic overprinting of the lithospheric mantle and enrichment of the lower crust by metallic elements, fluids, and volatiles from subducted slabs are preconditions for subsequent auriferous mineralization processes. The parental rocks of these Au deposits generally have a high O fugacity and are fractionated I-type or magnetite-series granites that have an affinity with the high-K calc-alkaline series, in which physicochemical parameters such as the O fugacity regulate the S speciation in the magmas and Au distribution. Furthermore, the timing of Au-bearing metallic sulfide saturation in the magmas and subsequent exsolution into the fluid phase is one of the critical controls on Au transportation into the shallow crust and its subsequent deposition in economically viable concentrations. Such Au deposits form mainly in transitional tectonic settings associated with slab subduction (e.g., slab rollback, break off) or during the transition from collisional to post-collisional tectonic settings. The physicochemical processes that govern melt segregation, differentiation, and Au enrichment from the magma source regions to final ore deposition have significant implications for understanding anomalous Au concentration mechanisms. The interrelationships among physicochemical parameters are the critical factor in understanding the coupling relationship between the melt-fluid evolution and Au mineralization, and therefore warrant further investigation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107145"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical and geochronological constraints on granitoids from the Chambishi-Nkana Basin, Zambian Copperbelt 赞比亚铜带Chambishi-Nkana盆地花岗岩类的地球化学和年代学约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107139
Hu Qiaofan , Mo Jiangping , Wei Zhiwei , Qiu ZhengJie , Fang Ke , Zhou Shouyu , Huang Xueqiang , Liu Yaohui , Liu Wei , Li Jiacai , Wang Ailin
This study focuses on the granitic intrusions in the Chambishi-Nkana Basin of the Zambian Copperbelt, aiming to reveal their genesis, tectonic setting, emplacement age, and relationship with Cu-Co mineralization. LA-ICP-MS zircon U-Pb dating shows that the Chambishi granite formed at approximately 1951 Ma, and the Nchanga granite crystallized at approximately 890 Ma. Geochemical analyses indicate that these rocks are peraluminous S-type granites, characterized by high A/CNK values (>1.3), enrichment in light rare earth elements, and significant negative Eu anomalies (Eu/Eu*=21.38–38.28). Zircon Lu-Hf isotopic data suggest that the Chambishi granite originated from the mixing of mantle and crust-derived melts during the collision between the Bangweulu Block and the Tanzania Craton, while the Nchanga granite formed from crustal anatexis without significant mantle input in an intraplate rift environment associated with the breakup of Rodinia in the Neoproterozoic. Molybdenite Re-Os dating reveals that hydrothermal cross-cutting vein-type Cu-Mo mineralization occurred at approximately 496 Ma, coinciding with basin inversion during the late stage of the Lufilian collisional orogeny—this age only represents the timing of the late vein-type mineralization, not the entire mineralization history of the deposit. This study confirms that the late Lufilian orogeny provided tectonic channels for hydrothermal migration, and granitic intrusions provided favorable structural channels for hydrothermal migration, while tectonic-thermal effects of the late Lufilian orogeny supplied the necessary thermal driving force, jointly controlling the formation of hydrothermal cross-cutting vein-type Cu-Mo mineralization. The sedimentary layered Cu-Co mineralization is controlled by the Neoproterozoic sedimentary environment, and its specific formation age requires further dating of sulfides (e.g., carrollite) in the layered mineralization. By integrating geochronological and geochemical data, this research establishes a temporal framework for magmatic events, tectonic evolution, and mineralization in the Zambian Copperbelt, highlighting the critical control of regional tectonic-magmatic activities on Cu-Co mineralization.
本文以赞比亚铜带Chambishi-Nkana盆地的花岗质侵入岩为研究对象,旨在揭示其成因、构造背景、侵位时代及其与Cu-Co矿化的关系。LA-ICP-MS锆石U-Pb测年表明谦比希花岗岩形成时间约为1951 Ma,恩昌加花岗岩结晶时间约为890 Ma。地球化学分析表明,这些岩石为过铝质s型花岗岩,具有高A/CNK值(>1.3)、富集轻稀土元素、显著负Eu异常(Eu/Eu*=21.38 ~ 38.28)的特征。锆石Lu-Hf同位素数据表明,谦比希花岗岩形成于Bangweulu地块与坦桑尼亚克拉通碰撞过程中地幔与壳源熔体的混合,而Nchanga花岗岩形成于新元古代与Rodinia分裂相关的板内裂谷环境中没有明显地幔输入的地壳深熔。辉钼矿Re-Os测年结果表明,热液横切脉状铜钼成矿发生在496 Ma左右,与陆菲连碰撞造山晚期的盆地反转相吻合,该年龄仅代表脉状晚期成矿的时间,不能代表矿床的全部成矿史。研究证实,晚鲁菲连造山运动为热液运移提供了构造通道,花岗岩侵入体为热液运移提供了有利的构造通道,而晚鲁菲连造山运动的构造-热效应提供了必要的热驱动力,共同控制了热液横切脉型铜钼矿化的形成。沉积层状铜钴矿化受新元古代沉积环境控制,其具体形成年代需要进一步确定层状矿化中硫化物(如卡罗尔石)的年代。结合地质年代学和地球化学资料,建立了赞比亚铜带岩浆事件、构造演化和成矿作用的时间框架,突出了区域构造岩浆活动对铜钴成矿作用的关键控制作用。
{"title":"Geochemical and geochronological constraints on granitoids from the Chambishi-Nkana Basin, Zambian Copperbelt","authors":"Hu Qiaofan ,&nbsp;Mo Jiangping ,&nbsp;Wei Zhiwei ,&nbsp;Qiu ZhengJie ,&nbsp;Fang Ke ,&nbsp;Zhou Shouyu ,&nbsp;Huang Xueqiang ,&nbsp;Liu Yaohui ,&nbsp;Liu Wei ,&nbsp;Li Jiacai ,&nbsp;Wang Ailin","doi":"10.1016/j.oregeorev.2026.107139","DOIUrl":"10.1016/j.oregeorev.2026.107139","url":null,"abstract":"<div><div>This study focuses on the granitic intrusions in the Chambishi-Nkana Basin of the Zambian Copperbelt, aiming to reveal their genesis, tectonic setting, emplacement age, and relationship with Cu-Co mineralization. LA-ICP-MS zircon U-Pb dating shows that the Chambishi granite formed at approximately 1951 Ma, and the Nchanga granite crystallized at approximately 890 Ma. Geochemical analyses indicate that these rocks are peraluminous S-type granites, characterized by high A/CNK values (&gt;1.3), enrichment in light rare earth elements, and significant negative Eu anomalies (Eu/Eu*=21.38–38.28). Zircon Lu-Hf isotopic data suggest that the Chambishi granite originated from the mixing of mantle and crust-derived melts during the collision between the Bangweulu Block and the Tanzania Craton, while the Nchanga granite formed from crustal anatexis without significant mantle input in an intraplate rift environment associated with the breakup of Rodinia in the Neoproterozoic. Molybdenite Re-Os dating reveals that<!--> <!-->hydrothermal cross-cutting vein-type Cu-Mo mineralization<!--> <!-->occurred at approximately 496 Ma, coinciding with basin inversion during the late stage of the Lufilian collisional orogeny—this age only represents the timing of the late vein-type mineralization, not the entire mineralization history of the deposit. This study confirms that the late Lufilian orogeny provided tectonic channels for hydrothermal migration, and granitic intrusions provided favorable structural channels for hydrothermal migration, while tectonic-thermal effects of the late Lufilian orogeny supplied the necessary thermal driving force, jointly controlling the formation of hydrothermal cross-cutting vein-type Cu-Mo mineralization. The sedimentary layered Cu-Co mineralization is controlled by the Neoproterozoic sedimentary environment, and its specific formation age requires further dating of sulfides (e.g., carrollite) in the layered mineralization. By integrating geochronological and geochemical data, this research establishes a temporal framework for magmatic events, tectonic evolution, and mineralization in the Zambian Copperbelt, highlighting the critical control of regional tectonic-magmatic activities on Cu-Co mineralization.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107139"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced SOTEM survey for the exploration of low-sulphidation epithermal gold: Insights from Lvyuan, eastern Junggar, China 准噶尔东部绿原地区低硫化浅成热液金超前SOTEM勘查研究
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107140
Weiying Chen , Xiaoyin Ma , Quanhui Guo , Pengfei Lv
The investigation of low-sulfidation epithermal gold deposits presents significant challenges due to their intricate geological frameworks and frequently obscured mineralization. This research details the implementation of the short-offset transient electromagnetic method (SOTEM) to concurrently invert resistivity and chargeability parameters within the Lvyuan Gold Deposit located in Eastern Junggar, China. Utilizing a grounded-wire source alongside dual-base-frequency transmission, high-fidelity electromagnetic data were collected across ten survey lines encompassing the No. 7 alteration zone. One-dimensional inversion of the transient electromagnetic responses elucidated detailed subsurface electrical structures to depths of approximately one kilometer, facilitating the identification of fault systems and alteration zones linked to gold mineralization. Measurements of rock physical properties substantiated that elevated chargeability values (>20%) combined with moderate to low resistivity (<300 Ω·m) are strongly indicative of hydrothermally altered lithologies, particularly those exhibiting pyritization and limonitization. Integration of these geophysical results with drilling data confirmed that mineralized bodies predominantly occur within shallow zones characterized by low resistivity and high chargeability proximal to fault structures. Consequently, four prospective target areas were delineated, underscoring the effectiveness of SOTEM in delineating alteration zones and informing subsequent exploration efforts for epithermal gold deposits.
低硫化浅成热液型金矿床地质格架复杂,矿化模糊,为其研究带来了重大挑战。本文详细介绍了利用短偏移瞬变电磁法(SOTEM)反演准噶尔东部绿园金矿的电阻率和电荷率参数。利用接地线源和双基频传输,在7号改造区周围的10条测量线上收集了高保真电磁数据。瞬变电磁响应的一维反演揭示了深度约1公里的详细地下电性结构,有助于识别与金矿化有关的断裂系统和蚀变带。岩石物理性质测量证实,较高的电荷率值(>20%)和中至低电阻率(<300 Ω·m)强烈表明热液蚀变岩性,特别是黄铁矿化和褐铁矿化。将这些地球物理结果与钻井数据相结合,证实矿化体主要分布在断层构造近端低电阻率和高电荷率的浅层带内。在此基础上,圈定了4个远景靶区,突出了瞬变电磁法圈定蚀变带的有效性,为后续的浅成低温热液金矿找矿提供了依据。
{"title":"Advanced SOTEM survey for the exploration of low-sulphidation epithermal gold: Insights from Lvyuan, eastern Junggar, China","authors":"Weiying Chen ,&nbsp;Xiaoyin Ma ,&nbsp;Quanhui Guo ,&nbsp;Pengfei Lv","doi":"10.1016/j.oregeorev.2026.107140","DOIUrl":"10.1016/j.oregeorev.2026.107140","url":null,"abstract":"<div><div>The investigation of low-sulfidation epithermal gold deposits presents significant challenges due to their intricate geological frameworks and frequently obscured mineralization. This research details the implementation of the short-offset transient electromagnetic method (SOTEM) to concurrently invert resistivity and chargeability parameters within the Lvyuan Gold Deposit located in Eastern Junggar, China. Utilizing a grounded-wire source alongside dual-base-frequency transmission, high-fidelity electromagnetic data were collected across ten survey lines encompassing the No. 7 alteration zone. One-dimensional inversion of the transient electromagnetic responses elucidated detailed subsurface electrical structures to depths of approximately one kilometer, facilitating the identification of fault systems and alteration zones linked to gold mineralization. Measurements of rock physical properties substantiated that elevated chargeability values (&gt;20%) combined with moderate to low resistivity (&lt;300 Ω·m) are strongly indicative of hydrothermally altered lithologies, particularly those exhibiting pyritization and limonitization. Integration of these geophysical results with drilling data confirmed that mineralized bodies predominantly occur within shallow zones characterized by low resistivity and high chargeability proximal to fault structures. Consequently, four prospective target areas were delineated, underscoring the effectiveness of SOTEM in delineating alteration zones and informing subsequent exploration efforts for epithermal gold deposits.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107140"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation of the Zarshuran gold deposit in northwest Iran resulted from the mixing of fertile magmatic fluids with basinal brines: Evidence from sulfide trace elements and sulfur isotopes 伊朗西北部扎尔舒兰金矿床的形成是由丰富的岩浆流体与盆地盐水混合形成的:来自硫化物微量元素和硫同位素的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107126
Shu Yang , Hongrui Zhang , Zhiming Yang , Pinghua Liu , Mehraj Aghazadeh , Zengqian Hou , Tiannan Yang , Zahra Badrzadeh
Zarshuran is the largest gold deposit in the Middle East. However, the sources of ore-forming materials at Zarshuran remain poorly understood. This study presents detailed descriptions of paragenetic sequence, in situ calcite U-Pb data, sulfide trace elements and sulfur isotope data to trace the sources of ore-forming materials and track the ore-forming processes. Calcite U-Pb results suggest the gold mineralization occurred during ca. 21–12.0 Ma. Five stages of mineralization can be divided at Zarshuran. They are characterized by pyrite grains with different textures. LA-ICP-MS analyses of the different types of pyrite demonstrate that Au is enriched in ore-stage Ⅰ, ore-stage Ⅱ, and late-ore stage. LA-ICP-MS analyses of the different types of sphalerite show an increasing trend for In and Sn contents but a decreasing trend for Ge and Tl contents from Sp1a to Sp1c. The S isotope compositions of sulfides from different stages yield positive values, suggesting these sulfides were precipitated by thermochemical sulfate reduction. Most δ34S values of sulfide minerals of the ore-stages are in the ranges between magmatic sulfur and redbeds sulfates sulfur, suggesting contributions of magmatic and basinal materials during mineralization. The shift of δ34S values during late-ore stage indicates the addition of Miocene seawater sulfates sulfur. We propose the Zarshuran gold mineralization was formed by mixing of magmatic fluids with basinal brines during the exhumation of the Iman Khan metamorphic core complex (MCC). The development of MCC and coeval fertile magmatism and basinal brine flow are important for exploration of Zarshuran-type gold ores.
扎舒兰是中东最大的金矿。然而,对扎树然成矿物质的来源仍然知之甚少。通过对共生序列、方解石U-Pb原位数据、硫化物微量元素和硫同位素数据的详细描述,追踪成矿物质来源和成矿过程。方解石U-Pb结果表明金矿化发生在约21 ~ 12.0 Ma。扎树然矿化可分为5期。它们的特点是黄铁矿颗粒具有不同的质地。不同类型黄铁矿的LA-ICP-MS分析表明,金富集于矿级Ⅰ、矿级Ⅱ和矿后期。不同类型闪锌矿的LA-ICP-MS分析表明,从Sp1a到Sp1c阶段,In和Sn含量呈上升趋势,Ge和Tl含量呈下降趋势。不同阶段硫化物的S同位素组成均为正值,表明这些硫化物是由硫酸盐热化学还原沉淀而成。各矿段硫化物矿物的δ34S值大多介于岩浆硫和红层硫酸盐硫之间,表明岩浆和盆地物质在成矿过程中起作用。矿石后期δ34S值的变化表明中新世海水硫酸盐硫的加入。本文认为,扎树然金矿化是在伊曼汗变质核杂岩(MCC)发掘过程中岩浆流体与盆地卤水混合作用形成的。中冶盆地的发育、同时期富岩浆活动和盆地卤水流的形成对扎树兰型金矿的找矿具有重要意义。
{"title":"Formation of the Zarshuran gold deposit in northwest Iran resulted from the mixing of fertile magmatic fluids with basinal brines: Evidence from sulfide trace elements and sulfur isotopes","authors":"Shu Yang ,&nbsp;Hongrui Zhang ,&nbsp;Zhiming Yang ,&nbsp;Pinghua Liu ,&nbsp;Mehraj Aghazadeh ,&nbsp;Zengqian Hou ,&nbsp;Tiannan Yang ,&nbsp;Zahra Badrzadeh","doi":"10.1016/j.oregeorev.2026.107126","DOIUrl":"10.1016/j.oregeorev.2026.107126","url":null,"abstract":"<div><div>Zarshuran is the largest gold deposit in the Middle East. However, the sources of ore-forming materials at Zarshuran remain poorly understood. This study presents detailed descriptions of paragenetic sequence, in situ calcite U-Pb data, sulfide trace elements and sulfur isotope data to trace the sources of ore-forming materials and track the ore-forming processes. Calcite U-Pb results suggest the gold mineralization occurred during ca. 21–12.0 Ma. Five stages of mineralization can be divided at Zarshuran. They are characterized by pyrite grains with different textures. LA-ICP-MS analyses of the different types of pyrite demonstrate that Au is enriched in ore-stage Ⅰ, ore-stage Ⅱ, and late-ore stage. LA-ICP-MS analyses of the different types of sphalerite show an increasing trend for In and Sn contents but a decreasing trend for Ge and Tl contents from Sp1a to Sp1c. The S isotope compositions of sulfides from different stages yield positive values, suggesting these sulfides were precipitated by thermochemical sulfate reduction. Most δ<sup>34</sup>S values of sulfide minerals of the ore-stages are in the ranges between magmatic sulfur and redbeds sulfates sulfur, suggesting contributions of magmatic and basinal materials during mineralization. The shift of δ<sup>34</sup>S values during late-ore stage indicates the addition of Miocene seawater sulfates sulfur. We propose the Zarshuran gold mineralization was formed by mixing of magmatic fluids with basinal brines during the exhumation of the Iman Khan metamorphic core complex (MCC). The development of MCC and coeval fertile magmatism and basinal brine flow are important for exploration of Zarshuran-type gold ores.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107126"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Ore Geology Reviews
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1