Effect of roasting on flavonoids, phenolics, and antioxidant activity of industrial-pulped and fermented cocoa beans

Food chemistry advances Pub Date : 2025-03-01 Epub Date: 2025-02-11 DOI:10.1016/j.focha.2025.100925
Bernard Kwabena Asiedu , Emmanuel Ohene Afoakwa , Crossby Osei Tutu , Rexford Obeng , Nii Korley Kortei , Papa Toah Akonor , Agnes Simpson Budu , Firibu Kwesi Saalia
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Abstract

The extent to which roasting of depulped cocoa beans at varied roasting intensities influences the total polyphenolic content, total flavonoid content, and DPPH scavenging capacity of cocoa liquor remains underexplored. This study investigated the effect of mechanical depulping and roasting intensities on these parameters in Ghanaian cocoa beans. A 3 × 3 full factorial design was employed, with depulping levels (0 %, 50 %, and 100 %) and roasting conditions (110 °C for 60 min, 120 °C for 30 min, and 135 °C for 10 min) as the principal factors. Cocoa beans were depulped mechanically, fermented for six days, dried at 55 °C to a moisture content of 7, 8 %, roasted, deshelled, and milled into cocoa liquor. The results showed that roasting intensity and mechanical depulping significantly influenced the studied parameters. Cocoa liquor obtained from mechanically depulped beans exhibited a higher total polyphenol content but lower flavonoid content and antioxidant capacity. Moderate roasting (120 °C for 30 min) and low-temperature, long-time (110 °C for 60 min) roasting processes preserved more flavonoids and antioxidant activity than high-temperature, short-time (135 °C for 10 min) roasting. These findings highlight the importance of optimizing depulping and roasting conditions to balance the retention of bioactive compounds and antioxidant properties in cocoa liquor.
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焙烧对工业浆和发酵可可豆类黄酮、酚类物质和抗氧化活性的影响
不同焙烧强度下脱浆可可豆的焙烧对可可液中总多酚含量、总黄酮含量和DPPH清除能力的影响程度尚不清楚。本研究考察了机械脱浆和焙烧强度对加纳可可豆这些参数的影响。采用3 × 3全因子设计,以脱浆水平(0%、50%和100%)和焙烧条件(110°C 60 min、120°C 30 min和135°C 10 min)为主要因素。可可豆机械脱浆,发酵6天,在55°C下干燥至水分含量为7.8%,烘烤,去壳,磨成可可液。结果表明,焙烧强度和机械脱浆对研究参数有显著影响。机械脱浆的可可液中总多酚含量较高,但类黄酮含量和抗氧化能力较低。适度焙烧(120°C 30分钟)和低温长时间焙烧(110°C 60分钟)比高温短时间(135°C 10分钟)焙烧保留了更多的黄酮类化合物和抗氧化活性。这些发现强调了优化脱浆和烘焙条件以平衡可可液中生物活性化合物的保留和抗氧化性能的重要性。
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来源期刊
Food chemistry advances
Food chemistry advances Analytical Chemistry, Organic Chemistry, Chemistry (General), Molecular Biology
CiteScore
1.90
自引率
0.00%
发文量
0
审稿时长
99 days
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