Assessment of polycyclic aromatic hydrocarbons (PAHs) and heavy metal contamination in Shitalakshya River water: ecological and health risk implications

Abstract

The Shitalakshya River, vital to the Dhaka district, faces severe pollution challenges due to industrial discharges, urban runoff, and other anthropogenic activities. This study investigated the concentration of polycyclic aromatic hydrocarbons (PAHs) and heavy metals in the river water, utilizing GC–MS/MS and ICP-MS techniques. The results revealed a total PAH concentration ranging from 4.97 to 5.87 ng/mL, with 3-ring PAHs being the most prevalent. Heavy metals such as Fe, As, Ni, and Zn were found in significant concentrations, exceeding international standards for drinking water and aquatic life. The ecological risk assessment identified benzo(b)fluoranthene, benzo(k)fluoranthene, and indeno(1,2,3-cd)pyrene as the highest threats to aquatic organisms. Health risk assessments indicated substantial risks from dermal and ingestion exposures, particularly due to arsenic, highlighting potential long-term health implications for local residents. The study underscores the urgent need for comprehensive monitoring, pollution source identification, and stringent regulatory measures to mitigate these risks.