Relating norbornene composition-to-reactivity for thiol–ene photopolymerizations and 3D printing†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-01-23 Epub Date: 2025-02-12 DOI:10.1039/d4cc06196a
Yutong Liu , Henry L. Cater , Elizabeth A. Recker , Zachariah A. Page
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Abstract

Structure–reactivity relationships for an array of norbornene derivatives in light-initiated thiol–ene reactions were unveiled using real-time Fourier-transform infrared (FTIR) spectroscopy. Guided by these results, poly(N-hydroxyethyl acrylamide) was functionalized with exo-norborneneimide and used in digital light processing (DLP) 3D printing of biomimetic hydrogels.

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降冰片烯组成与巯基光聚合和3D打印反应性的关系。
利用实时傅里叶变换红外(FTIR)光谱揭示了一系列降冰片烯衍生物在光引发的硫醇-烯反应中的结构-反应性关系。在这些结果的指导下,聚(n -羟乙基丙烯酰胺)被外降龙骨烯酰亚胺功能化,并用于仿生水凝胶的数字光处理(DLP) 3D打印。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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