Coordination bonds as a tool for tuning photoconductance in nanostructured hybrid materials made of molecular antennas and metal nanoparticles.

Abstract

The synthesis of robust, versatile materials in which electrical conduction is enhanced by light irradiation is of prime importance for fields as varied as photodetectors, photodiodes, solar cells and light sensors. Hybrid materials offer the advantage of combining the robustness of an inorganic building block with the adaptability of a molecular subunit. Herein, we demonstrate the importance of properly investigating the nature of the chemical interactions between the constituent elements in order to optimize photoconductance within hybrid materials. To this end, platinum nanoparticle self-assemblies are synthesized in solution, including a series of zinc-porphyrins differentially functionalized with pyridine moieties in the meso position. The presence of coordinating groups on the molecular entities drastically reinforced both the structural cohesion of the system and its photoconductive properties.