Real-Time Monitoring of Dissolved Oxygen Using a Novel Ground-Based Hyperspectral Proximal Sensing System

IF 4.3 Q1 ENVIRONMENTAL SCIENCES ACS ES&T water Pub Date : 2025-01-08 DOI:10.1021/acsestwater.4c00896
Xiayang Luo, Na Li*, Yunlin Zhang*, Yibo Zhang, Kun Shi, Boqiang Qin, Guangwei Zhu, Erik Jeppesen, Justin D. Brookes and Xiao Sun, 
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Abstract

High-frequency and high-precision dissolved oxygen (DO) monitoring is essential for lake health assessment, but it is limited by equipment and methods. This study developed a novel ground-based hyperspectral proximal sensing system (GHPSs) combined with machine learning methods for continuous monitoring of DO with an observation interval of 20 s. Five machine learning and deep learning models were calibrated and validated to estimate DO based on four combination scenarios of the GHPSs reflectance of 420–830 nm, chlorophyll-a (Chl-a), and water temperature (WTR). The results showed that a support vector machine model was preferred for DO estimation with satisfactory accuracy (R2 = 0.84, mean absolute percentage error = 0.12, and root mean square error = 1.15 mg/L) based on 11,131 in situ measurements. Multitemporal changes of DO concentration in Lake Taihu were obtained from October 2021 to December 2023 by applying the model, which suggested that the surface of Lake Taihu was hypoxic in 2.1% out of 754 days. Finally, the potential significance of monitoring real-time DO dynamics was elaborated under global warming. This study highlights the effectiveness, accuracy, and high frequency of novel GHPSs in real-time DO monitoring, which is crucial for predicting and early warning of lake pollution.

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基于新型地基高光谱近端传感系统的溶解氧实时监测
高频、高精度的溶解氧(DO)监测是湖泊健康评价的必要条件,但受设备和方法的限制。本研究开发了一种结合机器学习方法的新型地基高光谱近端遥感系统(ghps),用于观测间隔20 s的DO连续监测。基于420-830 nm的ghps反射率、叶绿素-a (Chl-a)和水温(WTR)的四种组合情景,对5种机器学习和深度学习模型进行了校准和验证。结果表明,基于11131个原位测量数据,支持向量机模型对DO的估计精度较好(R2 = 0.84,平均绝对百分比误差= 0.12,均方根误差= 1.15 mg/L)。应用该模型获得了2021年10月至2023年12月太湖DO浓度的多时间变化,结果表明,754天中,太湖表面缺氧的时间为2.1%。最后,阐述了在全球变暖背景下监测实时DO动态的潜在意义。该研究突出了新型ghps在实时DO监测中的有效性、准确性和高频率,这对湖泊污染的预测和预警至关重要。
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