Insights into clogging behavior of Al2O3-C and ZrO2-C submerged entry nozzle during continuous casting of ultra-low carbon steel

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-02-12 DOI:10.1016/j.corsci.2025.112777
Kaiwang Chen , Lei Yuan , Qiang Gu , Guoqi Liu , Jingkun Yu , Hongxia Li
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Abstract

The clogging behavior of a new ZrO2-C submerged entry nozzle (SEN) in the industrial production of ultra-low carbon steel was studied. The results revealed that, compared to the Al2O3-C SEN, the clogging thickness at the ZrO2-C SEN outlet was reduced by over 20 % to the formation of a dense protective layer composed of CaO-Al2O3-SiO2 at the interface near the molten steel. Additionally, the corrosion layer formed within the ZrO2-C SEN effectively prevented decarburization and diffusion of CO. The use of the ZrO2-C SEN improved the qualification rate of the liquid level fluctuation and the defect rate of the slab was reduced by approximately 17 %. The related reactions occurring inside the nozzle were simulated and compared with the experimental results in detail.
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超低碳钢连铸过程中Al2O3-C和ZrO2-C浸没入口喷嘴堵塞行为的研究
研究了一种新型ZrO2-C浸入式喷嘴在超低碳钢工业生产中的堵塞行为。结果表明,与Al2O3-C SEN相比,ZrO2-C SEN出口的堵塞厚度减少了20% %以上,在靠近钢水的界面处形成了由CaO-Al2O3-SiO2组成的致密保护层。此外,在ZrO2-C SEN内形成的腐蚀层有效地阻止了CO的脱碳和扩散。ZrO2-C SEN的使用提高了液面波动的合格率,使板坯的不良率降低了约17. %。对喷嘴内发生的相关反应进行了模拟,并与实验结果进行了详细的比较。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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