Thrifting iridium for hydrogen

IF 45.8 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Science Pub Date : 2025-02-13
Andrew D. Pendergast, Shannon W. Boettcher
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Abstract

Using renewable electricity to produce hydrogen fuel reduces reliance on fossil fuels. Proton exchange membrane water electrolyzers (PEMWEs) are the highest-performing commercialized technology (1). These devices split water into oxygen gas and hydrogen ions (protons) at the anode. The protons then migrate through an ion-conducting polymer membrane (ionomer) to be reduced to hydrogen gas at the cathode. The anode reaction’s harsh environment requires the use of precious-metal catalysts, such as iridium oxide (IrOx). Given the expense and scarcity, the design of electrodes that minimize the use of precious metals without compromising the requisite stability and activity is desired for large-scale hydrogen production (2, 3). On page 791 of this issue, Shi et al. (4) report that anchoring IrOx catalysts onto porous cerium-oxide (CeOx) supports maintains performance even with much reduced precious metal use.
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用铱换氢
使用可再生电力生产氢燃料减少了对化石燃料的依赖。质子交换膜水电解槽(PEMWEs)是性能最高的商业化技术(1)。这些设备在阳极将水分解成氧气和氢离子(质子)。然后质子通过离子导电聚合物膜(离聚体)迁移,在阴极还原为氢气。阳极反应的恶劣环境要求使用贵金属催化剂,如氧化铱(IrOx)。考虑到成本和稀缺性,在不影响必要稳定性和活性的情况下最大限度地减少贵金属使用的电极设计是大规模制氢所需要的(2,3)。在本期的第791页,Shi等人(4)报告说,将IrOx催化剂锚定在多孔氧化铈(CeOx)支架上,即使贵金属的使用大大减少,也能保持性能。
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来源期刊
Science
Science 综合性期刊-综合性期刊
CiteScore
61.10
自引率
0.90%
发文量
0
审稿时长
2.1 months
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