Low-cost crosslinked PVA membranes as alternative proton exchange membrane in hemodialysis wastewater fed bioelectrochemical fuel cells

IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Process Safety and Environmental Protection Pub Date : 2025-02-13 DOI:10.1016/j.psep.2025.106915
Bhanupriya Das , Mithilesh Pasawan , Chin Tsan Wang , K. Anki Reddy , Kha Lil Dinh , Satinder K. Brar , Vimal Katiyar , Shiao-Shing Chen
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Abstract

Hemodialysis (HD) is a highly water and electricity-consuming process. Untreated hemodialysis wastewater (HDWW) has high chemical oxygen demand when discharged at a temperature of 20–25 °C. It causes significant wastage of thermal energy posing a challenge in achieving zero liquid discharge (ZLD). Microbial Fuel Cells (MFCs) offers a ground-breaking solution for reusing HDWW, thereby reducing the carbon footprint of HD. However, MFCs are practically limited by cost of Nafion 117. In this study, Polyvinyl Alcohol (PVA) previously used in HD for the effective removal of creatinine and larger molecular weight pollutants, is utilized as Nafion-alternative proton exchange membrane by crosslinking PVA with 5 % glutaraldehyde to harvest bioelectricity from HDWW fed MFCs. The crosslinked PVA membrane achieved a remarkable power density of 320 mW/m² due to its low ohmic resistance of 68.97 Ω, as confirmed by EIS analysis. Additionally, the membrane cost is reduced by eight-fold compared to Nafion-117, making it economically feasible. Moreover, PVA's manufacturing process, which uses water as a solvent, requires no catalyst, and involves zero activation steps, is eco-friendly. Reutilizing HDWW with crosslinked PVA membrane in MFCs advances ZLD in HD by harnessing low-grade heat and generating bioelectricity, thus significantly reducing dialysis waste and its ecological impact.
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低成本交联聚乙烯醇膜作为血液透析废水生物电化学燃料电池的替代质子交换膜
血液透析(HD)是一个高度耗水和耗电的过程。未经处理的血液透析废水(HDWW)在20-25°C的温度下排放时具有高的化学需氧量。它造成了巨大的热能浪费,对实现零液体排放(ZLD)提出了挑战。微生物燃料电池(mfc)为HDWW的再利用提供了突破性的解决方案,从而减少了HDWW的碳足迹。然而,mfc实际上受到nationon117费用的限制。在本研究中,聚乙烯醇(PVA)以前用于HD中有效去除肌酐和较大分子量的污染物,通过将PVA与5 %戊二醛交联,作为nafion替代质子交换膜,从HDWW饲养的mfc中收集生物电。EIS分析表明,交联PVA膜具有68.97 Ω的低欧姆电阻,功率密度达到320 mW/m²。此外,与Nafion-117相比,膜成本降低了8倍,使其在经济上可行。此外,PVA的制造过程以水为溶剂,不需要催化剂,也不需要激活步骤,是环保的。在mfc中利用HDWW和交联PVA膜通过利用低热量和产生生物电来推进HD的ZLD,从而显著减少透析浪费及其对生态的影响。
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来源期刊
Process Safety and Environmental Protection
Process Safety and Environmental Protection 环境科学-工程:化工
CiteScore
11.40
自引率
15.40%
发文量
929
审稿时长
8.0 months
期刊介绍: The Process Safety and Environmental Protection (PSEP) journal is a leading international publication that focuses on the publication of high-quality, original research papers in the field of engineering, specifically those related to the safety of industrial processes and environmental protection. The journal encourages submissions that present new developments in safety and environmental aspects, particularly those that show how research findings can be applied in process engineering design and practice. PSEP is particularly interested in research that brings fresh perspectives to established engineering principles, identifies unsolved problems, or suggests directions for future research. The journal also values contributions that push the boundaries of traditional engineering and welcomes multidisciplinary papers. PSEP's articles are abstracted and indexed by a range of databases and services, which helps to ensure that the journal's research is accessible and recognized in the academic and professional communities. These databases include ANTE, Chemical Abstracts, Chemical Hazards in Industry, Current Contents, Elsevier Engineering Information database, Pascal Francis, Web of Science, Scopus, Engineering Information Database EnCompass LIT (Elsevier), and INSPEC. This wide coverage facilitates the dissemination of the journal's content to a global audience interested in process safety and environmental engineering.
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