Effect of tensile deformation on corrosion behavior of nitrogen-containing stainless steel bipolar plates in a simulated environment for proton exchange membrane fuel cells

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-05-01 Epub Date: 2025-02-12 DOI:10.1016/j.corsci.2025.112778
Zhuocheng Li , Jiashu Li , Wenxiang Zhu , Jingjing Jiao , Bin Wang , Yong Tian , Xu Yang , Lingxu Yang , Huijun Liu , Bingxing Wang
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Abstract

This study examined the influence of tensile deformation on the microstructure evolution and corrosion behaviors of novel nitrogen-containing austenitic stainless steel in a simulated cathode environment for proton exchange membrane fuel cells. The results indicated that at ≤ 30 % deformation, the corrosion resistance was improved with increasing deformation level. This was attributed to dislocations and subgrain refinement promoting the formation of Cr2O3 and CrN, which inhibited F- from attacking the passive film due to lower oxygen vacancy concentrations. At a deformation level of 50 %, excessive dislocations and internal stress decreased the stability of the passive film and consequently reduced the corrosion resistance.
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质子交换膜燃料电池模拟环境中拉伸变形对含氮不锈钢双极板腐蚀行为的影响
在质子交换膜燃料电池模拟阴极环境中,研究了拉伸变形对新型含氮奥氏体不锈钢微观组织演变和腐蚀行为的影响。结果表明:变形≤ 30 %时,随着变形程度的增加,耐蚀性提高;这是由于位错和亚晶细化促进了Cr2O3和CrN的形成,而低氧空位浓度抑制了F-对钝化膜的攻击。在50% %的变形水平下,过多的位错和内应力降低了钝化膜的稳定性,从而降低了耐腐蚀性。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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