Photochemical fabrication of metallic composites: Synergize metal growth with interfacial bonding by polymers

IF 4.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Refractory Metals & Hard Materials Pub Date : 2025-02-13 DOI:10.1016/j.ijrmhm.2025.107095
Zhi Zhao, Xuan Yao, Chao Hou, Tielong Han, Erqi Yang, Xiaotong Zheng, Xinyu Li, Xiaoyan Song
{"title":"Photochemical fabrication of metallic composites: Synergize metal growth with interfacial bonding by polymers","authors":"Zhi Zhao,&nbsp;Xuan Yao,&nbsp;Chao Hou,&nbsp;Tielong Han,&nbsp;Erqi Yang,&nbsp;Xiaotong Zheng,&nbsp;Xinyu Li,&nbsp;Xiaoyan Song","doi":"10.1016/j.ijrmhm.2025.107095","DOIUrl":null,"url":null,"abstract":"<div><div>Conventional fabrication methods for W<img>Cu composites possess several limitations on the ultimate densification and comprehensive performance of products. Here we propose an innovative protocol to prepare W<img>Cu via photochemical reactions at ambient conditions. Specifically engineered polymeric reagent guided the continuous growth of Cu within W matrix and enhanced the affinity among W/Cu phases, whose combination led to well densified W<img>Cu composite. Our strategy completely avoided thermally induced grain growth and flipped the immiscible nature of W/Cu interfaces. It was even possible to simultaneously fabricate and shape products using patterned light field. This strategy provides new insight on fabricating metallic composites.</div></div>","PeriodicalId":14216,"journal":{"name":"International Journal of Refractory Metals & Hard Materials","volume":"128 ","pages":"Article 107095"},"PeriodicalIF":4.6000,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Refractory Metals & Hard Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263436825000605","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Conventional fabrication methods for WCu composites possess several limitations on the ultimate densification and comprehensive performance of products. Here we propose an innovative protocol to prepare WCu via photochemical reactions at ambient conditions. Specifically engineered polymeric reagent guided the continuous growth of Cu within W matrix and enhanced the affinity among W/Cu phases, whose combination led to well densified WCu composite. Our strategy completely avoided thermally induced grain growth and flipped the immiscible nature of W/Cu interfaces. It was even possible to simultaneously fabricate and shape products using patterned light field. This strategy provides new insight on fabricating metallic composites.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
金属复合材料的光化学制造:金属生长与聚合物界面结合的协同作用
传统的钨铜复合材料制备方法在产品的最终致密性和综合性能方面存在一定的局限性。在此,我们提出了一种在环境条件下通过光化学反应制备WCu的创新方案。特殊设计的聚合试剂引导Cu在W基体内的持续生长,增强了W/Cu相之间的亲合力,使WCu复合材料致密化。我们的策略完全避免了热诱导的晶粒生长,并扭转了W/Cu界面的不混相性质。它甚至可以使用图案光场同时制造和塑造产品。该策略为金属复合材料的制造提供了新的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
文献相关原料
公司名称
产品信息
麦克林
Acrylamide
阿拉丁
Pentaethylenehexamine
阿拉丁
Sodium ascorbate
来源期刊
CiteScore
7.00
自引率
13.90%
发文量
236
审稿时长
35 days
期刊介绍: The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.
期刊最新文献
Effect of WC on grain refinement of binder alloy in EB-PBFed CuNiFeSnTi/WC/diamond composites Thermal shock induced evolution of microstructure and mechanical properties in ultrafine-grained tungsten alloys Processing and characterization of bicontinuous W50Cu composite produced by entangled fiber plasma sintering (ETFPS) route Microstructure and wear behavior of carbide-metal cermet materials with WB addition Microstructural evolution and transformation mechanisms of W and W-Y2O3 matrices under ultra-high temperature for nuclear thermal propulsion
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1