{"title":"Four Noncentrosymmetric Molybdophosphates Discovered by Chemical Substitution Strategy","authors":"Zhixia Gao, Ke Li, Hong Du, Tohtiaji Bahti","doi":"10.1039/d4dt03580a","DOIUrl":null,"url":null,"abstract":"Herein, four molybdophosphates, AxB4-xMo5P2O22 (A = Na, K, B = Rb, Cs), were synthesized by cation substitution. Compared with the parent compound A4Mo5P2O22 (A = Rb, Cs), the different cations result in the different polarity of the structural-functional primitive, ultimately influencing the nonlinear optical properties of AxB4-xMo5P2O22 (x = 1-4).","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":"129 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt03580a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Herein, four molybdophosphates, AxB4-xMo5P2O22 (A = Na, K, B = Rb, Cs), were synthesized by cation substitution. Compared with the parent compound A4Mo5P2O22 (A = Rb, Cs), the different cations result in the different polarity of the structural-functional primitive, ultimately influencing the nonlinear optical properties of AxB4-xMo5P2O22 (x = 1-4).
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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