Effect of manufacturing conditions on morphology development in rapid stamp formed polyamide/glass fibre composite laminate components

IF 8.1 2区材料科学 Q1 ENGINEERING, MANUFACTURING Composites Part A: Applied Science and Manufacturing Pub Date : 2025-02-13 DOI:10.1016/j.compositesa.2025.108804

Ellen L. Heeley , Neil Reynolds , William Hamby , Catherine A. Kelly , Michael J. Jenkins , Darren J. Hughes

{"title":"Effect of manufacturing conditions on morphology development in rapid stamp formed polyamide/glass fibre composite laminate components","authors":"Ellen L. Heeley , Neil Reynolds , William Hamby , Catherine A. Kelly , Michael J. Jenkins , Darren J. Hughes","doi":"10.1016/j.compositesa.2025.108804","DOIUrl":null,"url":null,"abstract":"<div><div>The effect of manufacturing conditions on the morphology of an industrially-processed 11-ply polyamide/glass fibre (PA66-GF60) laminate was investigated. Through-thickness temperature variation during the manufacturing process (pre-heating, stamp forming, demoulding) was revealed via eight inter-ply thermocouples. Thermal and X-ray analysis provided insights into process-induced polymer crystallinity and morphology through the laminate thickness. Cooling rates up to ∼ 2100 °C/min were observed in outer plies, compared to ∼ 420 °C/min for inner plies. A self-heating exothermal phenomenon was observed during crystallisation of the inner layers, leading to increased core crystallinity. X-ray diffraction revealed differences in preferred polymer orientation between the plies. For the inner plies, additional mobility from slower cooling leads to partially oriented crystallites along the glass fibre axis and a well-developed lamellar macromorphology. The rapidly cooled outer plies showed unoriented morphology, without long-range ordering. The work provides detailed understanding of polymer morphology for an industrially-relevant high-volume manufacturing process for thermoplastic matrix components.</div></div>","PeriodicalId":282,"journal":{"name":"Composites Part A: Applied Science and Manufacturing","volume":"192 ","pages":"Article 108804"},"PeriodicalIF":8.1000,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Part A: Applied Science and Manufacturing","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359835X25000983","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MANUFACTURING","Score":null,"Total":0}

引用次数: 0

Abstract

The effect of manufacturing conditions on the morphology of an industrially-processed 11-ply polyamide/glass fibre (PA66-GF60) laminate was investigated. Through-thickness temperature variation during the manufacturing process (pre-heating, stamp forming, demoulding) was revealed via eight inter-ply thermocouples. Thermal and X-ray analysis provided insights into process-induced polymer crystallinity and morphology through the laminate thickness. Cooling rates up to ∼ 2100 °C/min were observed in outer plies, compared to ∼ 420 °C/min for inner plies. A self-heating exothermal phenomenon was observed during crystallisation of the inner layers, leading to increased core crystallinity. X-ray diffraction revealed differences in preferred polymer orientation between the plies. For the inner plies, additional mobility from slower cooling leads to partially oriented crystallites along the glass fibre axis and a well-developed lamellar macromorphology. The rapidly cooled outer plies showed unoriented morphology, without long-range ordering. The work provides detailed understanding of polymer morphology for an industrially-relevant high-volume manufacturing process for thermoplastic matrix components.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Composites Part A: Applied Science and Manufacturing 工程技术-材料科学：复合

CiteScore

15.20

自引率

5.70%

发文量

492

审稿时长

30 days

期刊介绍： Composites Part A: Applied Science and Manufacturing is a comprehensive journal that publishes original research papers, review articles, case studies, short communications, and letters covering various aspects of composite materials science and technology. This includes fibrous and particulate reinforcements in polymeric, metallic, and ceramic matrices, as well as 'natural' composites like wood and biological materials. The journal addresses topics such as properties, design, and manufacture of reinforcing fibers and particles, novel architectures and concepts, multifunctional composites, advancements in fabrication and processing, manufacturing science, process modeling, experimental mechanics, microstructural characterization, interfaces, prediction and measurement of mechanical, physical, and chemical behavior, and performance in service. Additionally, articles on economic and commercial aspects, design, and case studies are welcomed. All submissions undergo rigorous peer review to ensure they contribute significantly and innovatively, maintaining high standards for content and presentation. The editorial team aims to expedite the review process for prompt publication.