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Structure-performance relationship of polypropylene/elastomer/carbon black composites as high voltage cable shielding layer 聚丙烯/弹性体/炭黑复合材料作为高压电缆屏蔽层的结构性能关系
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-24 DOI: 10.1016/j.compositesa.2024.108334
Xiyu Zhang , Shixun Hu , Shangshi Huang , Yuxiao Zhou , Wenjia Zhang , Changlong Yang , Chi Yao , Xinhua Dong , Qi Zhang , Mingti Wang , Jun Hu , Qi Li , Jinliang He

As polypropylene (PP) is a competitive insulating material for next generation high-voltage cable, the corresponding PP based cable semi-conductive shielding layer material needs to be developed. This paper developed an excellent material prescription and proposed an analytical method of structure-performance relationship for the application and the evaluation of PP-based cable shielding layer. First, PP/POE/CB and PP/SEBS/CB composites with different carbon black (CB) loading were prepared and their electrical and mechanical properties were compared. Through thermal analysis technique, crystalline property and thermal stability of the composites were studied in detail. And the synchrotron radiation X-ray scattering techniques were employed to analyze the distribution of carbon black in the blend semi-quantitatively. The analysis result turns out the enrichment of carbon black in POE phase and its instability at high temperature limits its application under cable operation conditions. In contrast, PP/SEBS/CB30phr is recommended for lower thermal deformation, lower PTC effect and better mechanical parameters.

聚丙烯(PP)是下一代高压电缆具有竞争力的绝缘材料,因此需要开发相应的聚丙烯基电缆半导电屏蔽层材料。本文为聚丙烯基电缆屏蔽层的应用和评价开发了一种优良的材料处方,并提出了结构性能关系的分析方法。首先,制备了不同炭黑(CB)含量的 PP/POE/CB 和 PP/SEBS/CB 复合材料,并比较了它们的电气和机械性能。通过热分析技术,详细研究了复合材料的结晶特性和热稳定性。并采用同步辐射 X 射线散射技术对混合材料中炭黑的分布进行了半定量分析。分析结果表明,炭黑在 POE 相中的富集及其在高温下的不稳定性限制了其在电缆运行条件下的应用。相比之下,PP/SEBS/CB30phr 具有更低的热变形、更低的 PTC 效应和更好的机械参数,因此值得推荐使用。
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引用次数: 0
Study on the composition-property relationships of basalt fibers based on symbolic regression and physics-informed neural network 基于符号回归和物理信息神经网络的玄武岩纤维成分-属性关系研究
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-24 DOI: 10.1016/j.compositesa.2024.108324
Xiaomeng Wang , Qianhua Kan , Michal Petru , Guozheng Kang

Despite the known influence of chemical composition on the mechanical properties of basalt fibers, a clear understanding of this relationship is lacking. Chemical composition analysis and mechanical property tests are performed on basalt fiber samples. Test data is collected from various countries and regions to expand the dataset. An improved Physics-Informed Neural Network (PINN) approach is specifically designed to address the complexities of this relationship. By incorporating physical models like the Makishima-Mackenzie model, Rocherulle model and a symbolic regression formula, the PINN leverages established physical principles to enhance its ability to understand the underlying mechanisms governing the influence of chemical composition on mechanical properties. This focus on physical mechanisms not only improves the interpretability of the model but also empowers it to make accurate predictions, as evidenced by the high squared correlation coefficients of 0.8767 and 0.8145 between predicted and experimental values of modulus and strength, respectively.

尽管化学成分对玄武岩纤维机械性能的影响众所周知,但对这种关系却缺乏清晰的认识。我们对玄武岩纤维样品进行了化学成分分析和机械性能测试。测试数据收集自不同国家和地区,以扩大数据集。改进的物理信息神经网络(PINN)方法专门用于解决这种关系的复杂性。通过结合牧岛-麦肯齐模型、罗舍鲁尔模型和符号回归公式等物理模型,PINN 利用既定的物理原理,提高了理解化学成分对机械性能影响的内在机制的能力。这种对物理机制的关注不仅提高了模型的可解释性,还使其能够做出准确的预测,模量和强度的预测值与实验值之间分别高达 0.8767 和 0.8145 的平方相关系数就是证明。
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引用次数: 0
Multifunctional composite phase change materials: Preparation, enhanced properties and applications 多功能复合相变材料:制备、增强性能和应用
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-24 DOI: 10.1016/j.compositesa.2024.108331
Yihang Li , Xiaoguang Zhao , Daokui Li , Xiaochao Zuo , Huaming Yang

Thermal energy harvesting, storage, conversion and utilization technologies based on phase change materials (PCMs) have received widely attention. The intelligent integration of PCMs with functional carriers or nano-additives enables the application of energy such as thermal, light, electricity and magnetism in different fields. Herein, we discuss strategies for the preparation of multifunctional composite PCMs with enhanced properties, including PCMs selection, encapsulation carrier design, thermal performance optimization, and functional integration methods. The latest progress of advanced applications of multifunctional composite PCMs in the fields of thermal management, thermal protection, medical, energy saving, and thermal camouflage is reviewed. The multifunctional design characteristics of PCMs for different applications are emphasized, as well as the relationship between the structure and thermo-physical properties of multifunctional composite PCMs. Finally, the remaining challenges of multifunctional composite PCMs and the fields that need to be broken through for advanced applications are envisioned.

基于相变材料(PCMs)的热能采集、存储、转换和利用技术受到广泛关注。通过将 PCM 与功能载体或纳米添加剂智能集成,可将热能、光能、电能和磁能等能量应用于不同领域。在此,我们将从 PCMs 选择、封装载体设计、热性能优化和功能集成方法等方面探讨制备性能增强型多功能复合 PCMs 的策略。综述了多功能复合 PCM 在热管理、热保护、医疗、节能和热伪装等领域的先进应用的最新进展。重点介绍了不同应用领域 PCM 的多功能设计特点,以及多功能复合 PCM 的结构与热物理性能之间的关系。最后,展望了多功能复合 PCM 尚存在的挑战以及先进应用需要突破的领域。
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引用次数: 0
Synergistic enhancement of strength and toughness of fiber-reinforced composites by constructing biomimetic intermittent porous structure 通过构建仿生物间歇多孔结构协同提高纤维增强复合材料的强度和韧性
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-24 DOI: 10.1016/j.compositesa.2024.108335
Yaozu Hui , Yijie Wang , Xiaoming Chen , Xin Wang , Yanjie Gao , Kaiqiang Wen , Siyi Cheng , Jie Zhang , Jinyou Shao

Achieving a balance between strength and toughness is a vital requirement for the development of high-performance fiber-reinforced composites. Inspired by nature, this study integrates biomimetic intermittent porous carbon nanotubes (PCNT) structure into the composite for synergistically enhancing its strength and toughness. It was found that the interfacial shear strength, interfacial fracture toughness, 45FBT tensile strength, and interlaminar fracture toughness of the intermittent porous structure-coated fiber/resin composites obtained significant increases of 63.4%, 107.7%, 31.2%, and 64.3% than the baseline composites, respectively. The strengthening effect was contributed by the synergistic enhancement of the interfacial bonding areas and mechanical interlocking morphologies, as well as the significant frictional stresses induced by the morphological mismatches between adjacent gaps. The toughening mechanism was associated with the micro-crack formation, the PCNT structure rupture, and the crack deflection during the crack propagation. This work provides a promising pathway to overcome the trade-off between strength and toughness.

实现强度和韧性之间的平衡是开发高性能纤维增强复合材料的重要要求。受大自然的启发,本研究将仿生间歇多孔碳纳米管(PCNT)结构融入复合材料中,以协同增强其强度和韧性。研究发现,间歇多孔结构涂覆纤维/树脂复合材料的界面剪切强度、界面断裂韧性、45FBT 拉伸强度和层间断裂韧性比基线复合材料分别显著提高了 63.4%、107.7%、31.2% 和 64.3%。这种增强效果得益于界面结合区域和机械互锁形态的协同增强,以及相邻间隙之间形态不匹配所引起的显著摩擦应力。增韧机制与微裂纹形成、PCNT 结构断裂以及裂纹扩展过程中的裂纹偏转有关。这项研究为克服强度和韧性之间的权衡问题提供了一条可行的途径。
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引用次数: 0
The percolation inception of the CNT-polymer nanocomposites with the magneto-electric field effects on the CNT subbands 磁电场对碳纳米管子带影响下的碳纳米管-聚合物纳米复合材料的渗流萌发过程
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-22 DOI: 10.1016/j.compositesa.2024.108332
Mojtaba Haghgoo , Reza Ansari , Mohammad Kazem Hassanzadeh-Aghdam , Jaehwan Kim

The percolation inception of CNT-polymer nanocomposites is studied considering the magneto-electric field effects on CNT subbands. The analytical model predicts the electrical conductivity where CNTs are modeled as slender rods with their geometric orientations as randomly distributed or aligned to transfer electrons at tunneling distance range. The tunneling effect takes into account the electron transmission between every linked pair of CNTs when evaluating electrical resistance. The subsequent CNT displacement computation and the resistance change comprise the other phase of the modeling approach. Piezoresistivity results of the analyses agree well with the experimental data when considering tunneling behavior in the percolation transition zone. The magnetic field enhances the field affected subbands and increases the electrical conductivity by enhancing the mobility of the charges. The results reveal that the efficiency of CNT network in transmitting charges is increased with higher aspect ratio CNTs that scaled the sensitivity to lower values.

考虑到磁场对碳纳米管子带的影响,研究了碳纳米管-聚合物纳米复合材料的渗流萌发。分析模型预测了导电性,其中 CNT 被模拟为细长棒,其几何取向为随机分布或排列,可在隧道距离范围内传输电子。在评估电阻时,隧道效应考虑了每对相连的 CNT 之间的电子传输。随后的 CNT 位移计算和电阻变化构成了建模方法的另一个阶段。在考虑渗滤过渡区的隧道行为时,分析得出的压阻率结果与实验数据十分吻合。磁场增强了受场影响的子带,并通过提高电荷的迁移率提高了导电率。结果表明,随着高宽比碳纳米管的增加,碳纳米管网络传输电荷的效率也会增加,从而使灵敏度降低。
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引用次数: 0
Experimental characterization methods and numerical models of woven composite preforms: A review 编织复合材料预型件的实验表征方法和数值模型:综述
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-22 DOI: 10.1016/j.compositesa.2024.108329
Tiantian Yang, Li Zhang, Zhixing Li, Kai Huang, Licheng Guo

The formation of woven preforms is crucial for the quality and performance of textile composites produced through the Liquid Composite Molding (LCM) process. However, the structure of the preform inevitably undergoes deformations during the weaving and forming processes, such as compression, misalignment, even wrinkle defects. Advanced experimental methods and effective numerical approaches are keys for characterizing the deformation behavior and revealing the underlying mechanisms of the woven preforms in the forming process. Initially, this review presents classical woven composite preforms. Then, advanced experimental methods for the woven preforms are provided and discussed based on the applied load. Moreover, numerical analysis approaches for preforms are summarized at different scales. Based on the above summaries, future research trends for experimental methods and numerical analysis approaches of woven preforms are proposed. These trends include the integrated multi-means characterization of deformation, improved mechanical tests, and simulation models combining machine learning algorithms and finite element methods.

编织预型件的成型对于通过液态复合材料成型(LCM)工艺生产的纺织复合材料的质量和性能至关重要。然而,在编织和成型过程中,预成型件的结构不可避免地会发生变形,如压缩、错位,甚至皱褶缺陷。先进的实验方法和有效的数值方法是表征变形行为和揭示编织预型件在成型过程中潜在机理的关键。本综述首先介绍了经典的编织复合材料预型件。然后,根据外加载荷提供并讨论了编织预型件的先进实验方法。此外,还总结了不同尺度预型件的数值分析方法。在上述总结的基础上,提出了编织预成型实验方法和数值分析方法的未来研究趋势。这些趋势包括变形的多手段综合表征、改进的机械测试以及结合机器学习算法和有限元方法的模拟模型。
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引用次数: 0
Mussel-adhesive chemistry inspired conductive hydrogel with self-adhesion, biocompatibility, self-recovery and fatigue-resistance performances as flexible sensing electronics 受贻贝粘合剂化学启发的导电水凝胶具有自粘性、生物相容性、自恢复性和抗疲劳性,可用作柔性传感电子元件
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-22 DOI: 10.1016/j.compositesa.2024.108330
Jingren Ma , Chunxiao Zheng , Ya Lu , Yiying Yue , Weisheng Yang , Changtong Mei , Xinwu Xu , Huining Xiao , Jingquan Han

Conductive hydrogels are ideal candidates for wearable strain sensors due to their intrinsic stretchability and conductivity. However, it’s still a challenge to fabricate a conductive hydrogel with a combination performance of high mechanical strength, self-adhesion, sensitivity, self-recovery capability, fatigue-resistant ability and biocompatibility. Herein, a dual-network hydrogel (TG/P-LP) composed of 2,2,6,6-tetra-methylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibers (TOCNs) supported graphene (GN), Laponite-oxidized polydopamine (LP) and polyacrylic acid-co-poly acrylamide (P) hydrogel matrix was synthesized via a facile in-situ radical polymerization process. The optimized biocompatible TG/P-LP hydrogel exhibits a high mechanical strength, self-adhesive performance, intrinsic self-recovery capability (95.7 % in 60 min) and anti-fatigue property. The hydrogel-based strain sensor exhibits a wide strain range (0 ∼ 600 %) and a high sensitivity (GF = 12). This work designs a novel hydrogel-based sensor with excellent mechanical properties, long-term fatigue resistance, high strain sensitivity and wearability, demonstrating enormous potential in the applications of human motion detection and human–machine interaction.

导电水凝胶具有固有的可拉伸性和导电性,是可穿戴应变传感器的理想候选材料。然而,如何制造出一种具有高机械强度、自粘性、灵敏度、自我恢复能力、抗疲劳能力和生物相容性等综合性能的导电水凝胶仍是一项挑战。本文通过简便的原位自由基聚合工艺,合成了一种由 2,2,6,6- 四甲基哌啶-1-氧(TEMPO)氧化纤维素纳米纤维(TOCNs)支撑石墨烯(GN)、皂石氧化聚多巴胺(LP)和聚丙烯酸-聚丙烯酰胺(P)水凝胶基质组成的双网络水凝胶(TG/P-LP)。优化后的生物相容性 TG/P-LP 水凝胶具有很高的机械强度、自粘性能、内在自我恢复能力(60 分钟内恢复 95.7%)和抗疲劳特性。该水凝胶应变传感器的应变范围广(0 ∼ 600 %),灵敏度高(GF = 12)。这项工作设计出了一种新型水凝胶传感器,它具有优异的机械性能、长期抗疲劳性、高应变灵敏度和可穿戴性,在人体运动检测和人机交互方面具有巨大的应用潜力。
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引用次数: 0
Understanding stiffness degradation of composite helical springs with multi-braided layers under impact 了解多编织层复合螺旋弹簧在冲击力作用下的刚度衰减情况
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-20 DOI: 10.1016/j.compositesa.2024.108327
Ling Chen , Wenjin Xing , Joel Chong , Qian Jiang , Yiwei Ouyang , Liwei Wu , Youhong Tang

Understanding stiffness degradation and developing suitable damage detection method for composite helical springs (CHSs) are important for their application and further development. In this study, a coupled plasticity-damage model for capturing stiffness degradation of CHSs with multi-braided layers (MBLs-CHS) is developed. Experimental results show that there is minor damage that only happens in the resin component of MBLs-CHS during impact. The element removal fraction in the simulation result is used to evaluate the damage severity, which is suggested to increase with impact energy (Ei) and decrease sequentially for CHSs with single, double, and triple braided layers (i.e., SCHS, DCHS, and TCHS). Specifically, damage severity of TCHS decreases by 51.3 % under 60 J impaction compared to that of SCHS. Finally, the time domain analysis method is introduced to monitor damage in real time. The amplitude intensity profiles under various Ei of CHSs have been fitted to predict the global stiffness degradation of CHSs in real time.

了解复合螺旋弹簧(CHS)的刚度退化并开发合适的损伤检测方法对其应用和进一步发展非常重要。本研究建立了一个塑性-损伤耦合模型,用于捕捉具有多编织层的复合螺旋弹簧(MBLs-CHS)的刚度退化。实验结果表明,在撞击过程中,只有 MBLs-CHS 的树脂成分会发生轻微损伤。模拟结果中的元素去除率被用来评估损坏严重程度,对于具有单层、双层和三层编织层的 CHS(即 SCHS、DCHS 和 TCHS),损坏严重程度随冲击能量(Ei)的增加而增加,并依次降低。具体而言,与 SCHS 相比,TCHS 在 60 J 冲击力下的损坏严重程度降低了 51.3%。最后,引入了时域分析方法来实时监测损坏情况。通过拟合 CHS 不同 Ei 下的振幅强度曲线,可以实时预测 CHS 的整体刚度退化。
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引用次数: 0
A round-robin study on the tensile characterization of single fibres: A multifactorial analysis and recommendations for more reliable results 关于单纤维拉伸特性的循环研究:多因素分析和获得更可靠结果的建议
IF 8.1 2区 材料科学 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-06-18 DOI: 10.1016/j.compositesa.2024.108323
Thomas Jeannin , Gilles Arnold , Alain Bourmaud , Stéphane Corn , Emmanuel De Luycker , Pierre J.J. Dumont , Manuela Ferreira , Camille François , Marie Grégoire , Omar Harzallah , Julie Heurtel , Sébastien Joannès , Antoine Kervoelen , Ahmad Rashed Labanieh , Nicolas Le Moigne , Florian Martoïa , Laurent Orgéas , Pierre Ouagne , Damien Soulat , Alexandre Vivet , Vincent Placet

In this benchmark, the tensile properties of three types of organic fibres – flax, hemp and aramid − were determined using single-fibre tensile tests performed by nine research groups. Flax and hemp were chosen due to their prevalence among European fibre plants. Aramid was selected for its synthetic nature and comparable dimensional properties. Due to the morphological complexity and variability of plant fibres, the scatter in the apparent tangent modulus and strength is more pronounced for flax and hemp compared to aramid. The primary source of scatter in the tensile properties results from human factors and experimental procedures, particularly regarding the fibre selection, the measurement of the fibre cross-sectional area and of the tensile strain. The post-processing procedure also turns out to be a key factor. Finally, recommendations and guidelines for best practices are proposed to reduce the main sources of dispersion associated with the reproducibility of single fibre tensile tests.

在这一基准中,九个研究小组通过单纤维拉伸试验确定了亚麻、大麻和芳纶这三种有机纤维的拉伸特性。选择亚麻和大麻是因为它们在欧洲纤维植物中很普遍。选择芳纶是因为其合成性质和可比较的尺寸特性。由于植物纤维的形态复杂多变,亚麻和大麻的表观切线模量和强度的分散性比芳纶更为明显。拉伸性能差异的主要来源是人为因素和实验程序,特别是纤维的选择、纤维横截面积的测量和拉伸应变的测量。后处理程序也是一个关键因素。最后,提出了最佳实践的建议和指南,以减少与单纤维拉伸试验的可重复性相关的主要分散源。
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引用次数: 0
Effect of plasma treatment on hygrothermal creep behaviour of flax fibre composite 等离子处理对亚麻纤维复合材料湿热蠕变行为的影响
IF 8.1 2区 材料科学 Q1 Engineering Pub Date : 2024-06-17 DOI: 10.1016/j.compositesa.2024.108322
Jianqun Hao , Julien Bardon , Grégory Mertz , C.A. Fuentes , Aart Willem Van Vuure

Atmospheric plasma activation and plasma coating with 3-aminopropyltriethoxysilane (APTES) were used to investigate the effect of a modified interface on the creep behaviour of flax fibre reinforced polyoxymethylene composite. The wetting parameters and the interfacial shear strength indicate that using air-based plasma activation is superior to plasma coating with APTES when improvement of interface and mechanical properties are concerned. Hygrothermal creep tests within the linear viscoelastic region reveal that the creep resistance of air plasma treated composites is significantly enhanced, evidenced by reduced instantaneous strain and slower viscoelastic flow when compared to the untreated composites. However, creep rupture (run to failure) tests demonstrate that the air plasma treatment extends the creep lifespan only under standard conditions (50 % RH and 23 °C). Under severe conditions (85 % RH and 23 °C), plasma-treated composites exhibit a somewhat shorter lifespan, possibly because some damage induced by the plasma treatment is exacerbated at high humidity.

研究人员利用大气等离子活化和 3-aminopropyltriethoxysilane (APTES) 等离子涂层研究了改性界面对亚麻纤维增强聚甲醛复合材料蠕变行为的影响。润湿参数和界面剪切强度表明,在改善界面和机械性能方面,使用气基等离子活化优于使用 APTES 的等离子涂层。线性粘弹性区域内的湿热蠕变测试表明,与未经处理的复合材料相比,经过空气等离子体处理的复合材料的抗蠕变性明显增强,表现为瞬时应变降低,粘弹性流动减慢。然而,蠕变断裂(运行至破坏)测试表明,空气等离子处理仅在标准条件(50 % 相对湿度和 23 °C)下延长了蠕变寿命。在苛刻条件下(85 % 相对湿度和 23 °C),经过等离子处理的复合材料的寿命稍短,这可能是因为在高湿度条件下,等离子处理引起的某些损坏会加剧。
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引用次数: 0
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Composites Part A: Applied Science and Manufacturing
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