Penning source of hydrogen negative ions testing at different gases injection and optional application of ZrV cathodes

IF 8.3 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2025-03-14 Epub Date: 2025-02-18 DOI:10.1016/j.ijhydene.2025.02.222
I. Sereda , Y. Hrechko , M. Azarenkov , K. Sereda
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Abstract

A common challenge in hydrogen negative ions (H ions) production in a plasma volume is achieving the high concentration of vibrationally excited gas molecules. This study directly demonstrates the advantage of using the metal hydride based on ZrV alloy for H ions creation due to the hydrogen molecules releasing already in the vibrationally excited state. Using the Penning discharge with Zr50V50 cathodes driven at the low pressure (10 mPa) and the high voltage (5 kV) we have shown an almost doubling of extracted H current to 30 μA against to Cu cathodes at the same power of 10 W loaded in hydrogen plasma. Considering the tiny value (5 μA) of extracted negative current from the plasma generated on the gases (He, N2, Ar) which cannot produce enough negative ions, the application of the metal hydride can improve the volume ionization and gas efficiency in existed negative ion source.

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彭宁源氢负离子在不同气体注入下的测试及ZrV阴极的选配应用
在等离子体体积中产生氢负离子(H -离子)的一个共同挑战是实现高浓度的振动激发气体分子。该研究直接证明了使用基于ZrV合金的金属氢化物产生H离子的优势,因为氢分子已经在振动激发态释放。用低压(10 mPa)和高压(5 kV)驱动Zr50V50阴极进行Penning放电,结果表明,在相同功率(10 W)的氢等离子体负载下,相对于Cu阴极,提取的H -电流几乎增加了一倍,达到30 μA。考虑到He、N2、Ar等气体产生的等离子体中提取的负电流很小(5 μA),不能产生足够的负离子,金属氢化物的应用可以提高现有负离子源的体积电离和气体效率。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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