Design and synthesis of non-homogeneous CoS2/carbon composite nanofibers for enhanced microwave absorption

IF 11.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Pub Date : 2025-03-20 Epub Date: 2025-02-15 DOI:10.1016/j.carbon.2025.120120
Lei Zhang , Yashan Huo , Yang Liu , Minshan Zhao , Yujia Tan , Siyuan Huo , Li Yao , Shaohua Qu , Zhihui He
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Abstract

This paper presents a novel composite material composed of cobalt sulfide (CoS2) and carbon nanofibers, designed for efficient microwave absorption. Through electrospinning and high-temperature processing, CoS2 nanoparticles are embedded within porous carbon fibers, forming non-homogeneous CoS2 composite nanofibers. The material demonstrates outstanding microwave absorption properties, achieving a minimum reflection loss of −59.84 dB at 11.1 GHz and an effective microwave absorption bandwidth of 4.9 GHz. To investigate the structure and properties of CoS2/carbon composite nanofibers, multiple characterization techniques were utilized, and the results revealed the uniform distribution of CoS2 nanoparticles and their interaction with carbon fibers. Additionally, theoretical calculations were carried out to analyze the material's electronic structure and dielectric properties, shedding light on the polarization and conduction loss mechanisms that contribute to microwave attenuation. Radar cross-section (RCS) simulations further show that CoS2/carbon composite nanofibers can significantly reduce the strong electromagnetic scattering of the metal backplane, demonstrating its potential in avoiding radar wave detection. By examining impedance matching and electromagnetic attenuation mechanisms, this study provides valuable insights for the development of advanced microwave absorbers.

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增强微波吸收的非均相CoS2/碳复合纳米纤维的设计与合成
本文提出了一种由硫化钴(CoS2)和纳米碳纤维组成的新型微波吸收复合材料。通过静电纺丝和高温处理,将CoS2纳米颗粒嵌入多孔碳纤维中,形成非均匀的CoS2复合纳米纤维。该材料具有优异的微波吸收性能,在11.1 GHz时的最小反射损耗为- 59.84 dB,有效微波吸收带宽为4.9 GHz。为了研究CoS2/碳复合纳米纤维的结构和性能,采用了多种表征技术,揭示了CoS2纳米颗粒的均匀分布及其与碳纤维的相互作用。此外,还进行了理论计算,分析了材料的电子结构和介电性能,揭示了导致微波衰减的极化和传导损耗机制。雷达截面(RCS)模拟进一步表明,CoS2/碳复合纳米纤维可以显著降低金属背板的强电磁散射,显示其在躲避雷达波检测方面的潜力。通过研究阻抗匹配和电磁衰减机制,本研究为开发先进的微波吸收器提供了有价值的见解。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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