Ionic porous materials: from synthetic strategies to applications in gas separation and catalysis

Abstract

Ionic porous materials possess a unique combination of tunable pore sizes and task-specific interactions between guest molecules and the charged frameworks, which endow them with versatility across diverse domains in chemistry and materials science. Significant advancements in their applications for gas separation and catalysis have been achieved in recent years due to the incorporation of ionic functionalities and ultra-microporous structures that enable molecular-scale recognition of guest molecules. This review summarizes recent advancements in the synthetic strategies of ionic porous materials, establishing design guidelines for the incorporation of ionic moieties into the backbone to fine-tune pore sizes and chemistry. It highlights the synergistic interplay of task-specific interactions with custom-designed pore structures in key applications, including adsorption separation, membrane separation, and gas conversion. Additionally, it examines structure–property relationships, offering deeper insights into enhancing performance. The report also addresses the current challenges in the practical application of these materials. Finally, the review provides future perspectives on ionic porous materials from both scientific and industrial viewpoints. Overall, this review aims to provide insights into pore structure and chemistry, supporting the precise placement of ionic functionalities.