{"title":"Redox chemistry of cyclotetraborane","authors":"Zhongtao Feng , Rei Kinjo","doi":"10.1016/j.chempr.2025.102433","DOIUrl":null,"url":null,"abstract":"<div><div>In this issue of <em>Chem</em>, Braunschweig et al. report the selective synthesis of an electron-precise tetra(amino)tetraborane featuring a puckered B<sub>4</sub> ring. Chemical redox reactions lead to the stable radical anion, dianion, and radical cation. The four charge states of the B<sub>4</sub> ring are poised to spark a revolution in boron chemistry.</div></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":"11 3","pages":"Article 102433"},"PeriodicalIF":19.6000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929425000233","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
In this issue of Chem, Braunschweig et al. report the selective synthesis of an electron-precise tetra(amino)tetraborane featuring a puckered B4 ring. Chemical redox reactions lead to the stable radical anion, dianion, and radical cation. The four charge states of the B4 ring are poised to spark a revolution in boron chemistry.
期刊介绍：
Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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