Preparation and anti-corrosion properties of superamphiphobic aluminum alloy surfaces by iron salt etching

IF 2.7 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Letters Pub Date : 2025-02-17 DOI:10.1016/j.matlet.2025.138257
Xueyuan Jia, Yacheng Xu, Rongjie Gao
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Abstract

Superamphiphobic surfaces were prepared on 5052 aluminum alloy substrates by combining iron salt etching and water bath process. After modification, the contact angles of this surface with water and ethylene glycol reached 157.5° and 152.5°, respectively. And the sliding angle was 1°, exhibiting excellent superamphiphobicity. In comparison to the substrate, the corrosion potential of the superamphiphobic sample shifted positively by 745 mV, and the corrosion current density reduced from 3.745 × 10−6 A·cm−2 to 5.395 × 10−9 A·cm−2. Besides, the anti-corrosion performance was still superior to the substrate after a 7-day immersion in 3.5 wt% NaCl solution.

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铁盐蚀刻法制备超疏磷铝合金表面及其抗腐蚀性能
采用铁盐蚀刻和水浴相结合的方法在5052铝合金衬底上制备了超双疏表面。改性后,该表面与水和乙二醇的接触角分别达到157.5°和152.5°。滑动角为1°,表现出优异的超疏水性。与衬底相比,超双疏样品的腐蚀电位正移动745 mV,腐蚀电流密度从3.745 × 10−6 A·cm−2降低到5.395 × 10−9 A·cm−2。此外,在3.5 wt% NaCl溶液中浸泡7天后,其防腐性能仍优于基体。
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来源期刊
Materials Letters
Materials Letters 工程技术-材料科学:综合
CiteScore
5.60
自引率
3.30%
发文量
1948
审稿时长
50 days
期刊介绍: Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials. Contributions include, but are not limited to, a variety of topics such as: • Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors • Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart • Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction • Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots. • Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing. • Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic • Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive
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