Efficiency enhancement in 4T perovskite/Si tandem solar cell by charge extraction management

Abstract

High power conversion efficiency in 4-terminal perovskite/silicon tandem solar cells depends on minimizing optical losses and enhancing charge extraction in both sub-cells. Here, partially passivated nanorods with hexagonal and honeycomb lattice patterns are employed, for the first time as an electron-transporting layer in the top cell. This leads to compensation of the resistive losses and improves the charge extraction process which results in the enhancement of the fill factor while preserving V_oc. Also, interdigitated back contact has been implemented in the bottom cell to eliminate the shadowing effect and reduce the parasitic absorption. Additionally, the Si₃N₄ anti-reflection coating decreases optical losses in the bottom cell. The optimal structural specifications for rods at the top cell with a hexagonal pattern are r = 75 nm and a = 750 nm for the rod's radii and lattice constant, respectively in a 600 nm perovskite layer. Also, the interdigitated back contact bottom cell with the Si layer thickness of 290 μm was optimized for W_n/W_p = 0.2 and Gap = 5 μm. Cascading the proposed optimal sub-cells in a 4-terminal configuration led to the highest power conversion efficiency of 30.73 % ever reported, with the top and bottom cells contributing 23.34 % and 7.39 % to the overall efficiency, respectively to the best of the author's knowledge.