{"title":"Stability strategies for perovskite solar cells: From counter electrode materials aspect","authors":"Xiangming Xiong, Ying Yang, Congtan Zhu, Hui Zhang, Lin Zhang, Xueyi Guo","doi":"10.1016/j.ccr.2025.216499","DOIUrl":null,"url":null,"abstract":"<div><div>Perovskite Solar Cells (PSCs) have attracted extensive attention due to their high power conversion efficiency. However, high-efficiency PSCs generally use precious metal materials such as gold and silver to prepare the counter electrode, which leads to high cost and insufficient stability problems. In the search for alternative electrodes, inexpensive transition metals, carbon materials and composite materials show great potential. In this review, the influence of counter electrode materials on the photovoltaic performance and stability of PSCs is systematically analyzed. Especially, the origins for the poor stability of device with precious metals and inferior efficiency of device with non-precious metals and carbon materials are deeply explored. The corresponding stability strategies for improving the performances of PSCs with various types of counter electrode are introduced. The application of non-precious metal electrode materials is prospected, which is promising for the future PSCs development.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"532 ","pages":"Article 216499"},"PeriodicalIF":23.5000,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854525000694","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Perovskite Solar Cells (PSCs) have attracted extensive attention due to their high power conversion efficiency. However, high-efficiency PSCs generally use precious metal materials such as gold and silver to prepare the counter electrode, which leads to high cost and insufficient stability problems. In the search for alternative electrodes, inexpensive transition metals, carbon materials and composite materials show great potential. In this review, the influence of counter electrode materials on the photovoltaic performance and stability of PSCs is systematically analyzed. Especially, the origins for the poor stability of device with precious metals and inferior efficiency of device with non-precious metals and carbon materials are deeply explored. The corresponding stability strategies for improving the performances of PSCs with various types of counter electrode are introduced. The application of non-precious metal electrode materials is prospected, which is promising for the future PSCs development.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.