Stability strategies for perovskite solar cells: From counter electrode materials aspect

IF 23.5 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Coordination Chemistry Reviews Pub Date : 2025-02-18 DOI:10.1016/j.ccr.2025.216499
Xiangming Xiong, Ying Yang, Congtan Zhu, Hui Zhang, Lin Zhang, Xueyi Guo
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Abstract

Perovskite Solar Cells (PSCs) have attracted extensive attention due to their high power conversion efficiency. However, high-efficiency PSCs generally use precious metal materials such as gold and silver to prepare the counter electrode, which leads to high cost and insufficient stability problems. In the search for alternative electrodes, inexpensive transition metals, carbon materials and composite materials show great potential. In this review, the influence of counter electrode materials on the photovoltaic performance and stability of PSCs is systematically analyzed. Especially, the origins for the poor stability of device with precious metals and inferior efficiency of device with non-precious metals and carbon materials are deeply explored. The corresponding stability strategies for improving the performances of PSCs with various types of counter electrode are introduced. The application of non-precious metal electrode materials is prospected, which is promising for the future PSCs development.
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过氧化物太阳能电池的稳定性策略:从对电极材料入手
钙钛矿太阳能电池(PSCs)因其高功率转换效率而受到广泛关注。然而,高效的PSCs一般采用金、银等贵金属材料制备对电极,存在成本高、稳定性不足等问题。在寻找替代电极的过程中,廉价的过渡金属、碳材料和复合材料显示出巨大的潜力。本文系统分析了对极材料对聚苯乙烯复合材料光伏性能和稳定性的影响。特别对贵金属器件稳定性差、非贵金属和碳材料器件效率差的原因进行了深入探讨。介绍了相应的稳定性策略,以提高具有不同类型对电极的PSCs的性能。对非贵金属电极材料的应用前景进行了展望,认为非贵金属电极材料的应用前景广阔。
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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