Preparation of novel silica mannich base nanoparticles and corrosion inhibition properties on N80 steel under high acidic conditions

IF 6.3 2区材料科学 Q2 CHEMISTRY, PHYSICAL Applied Surface Science Pub Date : 2025-02-18 DOI:10.1016/j.apsusc.2025.162715

Chaocheng Ma, Zhengfeng Xie, Junming Miao, Wei Shi, Songsong Xue

{"title":"Preparation of novel silica mannich base nanoparticles and corrosion inhibition properties on N80 steel under high acidic conditions","authors":"Chaocheng Ma, Zhengfeng Xie, Junming Miao, Wei Shi, Songsong Xue","doi":"10.1016/j.apsusc.2025.162715","DOIUrl":null,"url":null,"abstract":"A novel organic nano-silicon material (NPs-SM) was synthesized by Mannich reaction using acetophenone, formaldehyde and amino silicon nanoparticles (Si NPs), which was prepared by KH550 and ascorbic acid through a simple one-step procedure. NPs-SM was characterized by FT-IR, XPS, SEM-EDS and TEM and studied of its slow-release performance. The inhibition efficiency was investigated with electrochemical impedance spectroscopy, potentiodynamic measurements, and mass loss analysis, respectively. Additionally, SEM, XPS, AFM and CA analyses were carried out to study the relationship between structural details and surficial performance of the protective layer formed on the steel. Intriguingly, the corrosion inhibition efficiency of NPs-SM significantly increases with increasing temperature in strong acid environments, reaching 94.94 %. This precisely matches the characteristics required for high-temperature and high acid corrosion inhibitors, this study is expected to provide new ideas for corrosion research under special conditions.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"24 1","pages":""},"PeriodicalIF":6.3000,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Surface Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.apsusc.2025.162715","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

A novel organic nano-silicon material (NPs-SM) was synthesized by Mannich reaction using acetophenone, formaldehyde and amino silicon nanoparticles (Si NPs), which was prepared by KH550 and ascorbic acid through a simple one-step procedure. NPs-SM was characterized by FT-IR, XPS, SEM-EDS and TEM and studied of its slow-release performance. The inhibition efficiency was investigated with electrochemical impedance spectroscopy, potentiodynamic measurements, and mass loss analysis, respectively. Additionally, SEM, XPS, AFM and CA analyses were carried out to study the relationship between structural details and surficial performance of the protective layer formed on the steel. Intriguingly, the corrosion inhibition efficiency of NPs-SM significantly increases with increasing temperature in strong acid environments, reaching 94.94 %. This precisely matches the characteristics required for high-temperature and high acid corrosion inhibitors, this study is expected to provide new ideas for corrosion research under special conditions.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Applied Surface Science 工程技术-材料科学：膜

CiteScore

12.50

自引率

7.50%

发文量

3393

审稿时长

67 days

期刊介绍： Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.