Physical Cross-Linking of Cellulose Nanofibrils with Zein Particles as an Eco-Friendly Detergent.

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2025-03-04 Epub Date: 2025-02-18 DOI:10.1021/acs.langmuir.4c04398
Wenli Liu, Wenxue Wang, Yanru Cui, Jiayu Liu, Pengtao Liu
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Abstract

Pickering particles can self-assemble to form a rigid barrier film at the oil-water interface, effectively inhibiting droplet aggregation and stabilizing the emulsion. This essay explores the potential of Zein/TOCNF (TEMPO-oxidized cellulose nanofiber) complex aqueous dispersion as an environmentally friendly, nontoxic, versatile, and inexpensive cleaning agent based on the Pickering effect. The Zein/TOCNF complex exhibited an improvement in its surface hydrophobicity compared to that of pure TOCNF, so that it could be used as Pickering emulsion stabilizers. The Zein/TOCNF complex has better washing ability than the washing powder for the removal of the dirt from the cotton cloth, the glass, the stainless steel, the ceramic, and the plastic sheet. In addition, residual amounts of Zein/TOCNF complexes on the fabric were insignificant. Moreover, research results have shown that Zein/TOCNF complexes are feasible as a secure, cost-effective, and sustainable alternative to commercial washing cleaners.

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纤维素纳米原纤维与玉米蛋白颗粒的物理交联作为环保洗涤剂。
酸洗颗粒可自组装,在油水界面形成刚性屏障膜,有效抑制液滴聚集,稳定乳状液。基于皮克林效应,本文探讨了玉米蛋白/TOCNF (temo氧化纤维素纳米纤维)复合水分散体作为一种环保、无毒、多功能、廉价的清洗剂的潜力。与纯TOCNF相比,玉米蛋白/TOCNF配合物的表面疏水性得到了改善,可以作为Pickering乳液稳定剂。Zein/TOCNF复合物对棉布、玻璃、不锈钢、陶瓷、塑料片材等表面污垢的去除能力优于洗衣粉。此外,Zein/TOCNF复合物在织物上的残留量不显著。此外,研究结果表明,玉米蛋白/TOCNF配合物作为一种安全、经济、可持续的商业洗涤剂替代品是可行的。
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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