Physicochemical, water, thermal and mechanical properties of cellulosed-based Kraft paper produced from five Malaysian bamboo species

IF 6.5 Q1 CHEMISTRY, APPLIED Carbohydrate Polymer Technologies and Applications Pub Date : 2025-03-01 Epub Date: 2025-02-19 DOI:10.1016/j.carpta.2025.100723
H.S.N. Hawanis , R.A. Ilyas , R. Jalil , R. Ibrahim , R.A. Majid , N.H. Ab Hamid , M.N.F. Norrrahim , V.F. Knight
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Abstract

This study focuses on the chemical composition, physicochemical properties, water-holding capacity, thermal behaviour, and physical and mechanical characteristics of native bamboo species in Malaysia. The species examined include Gigantochloa scortechinii (GS), Gigantochloa wrayi (GW), Gigantochloa levis (GL), Schizostachyum grande (SG), and Dendrocalamus asper (DA), chosen for their abundance and distribution in bamboo plantations. The Kraft pulping process, which utilizes alkaline treatment with sodium hydroxide and sodium sulphide at a sulphidity level of 25 %, is designed to dissolve lignin and convert bamboo into fibrous pulp suitable for papermaking. The effects of Kraft pulping were found to be beneficial to the GL bamboo species by producing the highest mechanical properties among all other bamboo species. Specifically, GL demonstrates tear index, tensile index, and number of folds values at 26.11 ± 1.79 mN.m2/g, 31.83 ± 0.09 Nm/g, and 24.87 ± 6.85, respectively. The utilization of Kraft pulping with a sulphidity of 25 % presents a promising potential for processing all five native Malaysian bamboo species into paper. This comparative analysis serves to deepen our comprehension of the effects of Kraft pulping on paper properties and provides valuable insights into harnessing bamboo fibers for sustainable pulp and paper production.

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由五种马来西亚竹子制成的纤维素基牛皮纸的物理化学、水、热和机械性能
本研究的重点是化学成分,理化性质,保水能力,热行为,物理和机械特性的马来西亚本地竹物种。研究物种包括巨石藻(Gigantochloa scortechinii, GS)、巨石藻(Gigantochloa wrayi, GW)、巨石藻(Gigantochloa levis, GL)、Schizostachyum grande (SG)和Dendrocalamus asper (DA)。卡夫制浆工艺采用氢氧化钠和硫化钠的碱性处理,硫化钠的硫化度为25%,旨在溶解木质素,将竹子转化为适合造纸的纤维纸浆。硫酸盐制浆对GL竹材有利,其机械性能在其他竹材中最高。具体来说,GL在26.11±1.79 mN时显示撕裂指数、拉伸指数和折叠数值。m2/g、31.83±0.09 Nm/g、24.87±6.85。硫酸盐浆的利用率为25%,为所有五种马来西亚本地竹子的造纸提供了良好的潜力。这种比较分析有助于加深我们对硫酸盐制浆对纸张性能的影响的理解,并为利用竹纤维进行可持续的纸浆和纸张生产提供了有价值的见解。
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