Search for Thiol-Protected Gold Clusters Doped with Different Elements Using Dendrimers

IF 2.7 4区 化学 Q3 POLYMER SCIENCE Macromolecular Chemistry and Physics Pub Date : 2024-11-27 DOI:10.1002/macp.202400334
Hisanori Muramatsu, Tetsuya Kambe, Takamasa Tsukamoto, Takane Imaoka, Kimihisa Yamamoto
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Abstract

The synthesis of thiol-protected Au clusters MAu24(SR)18 containing different elements (M: different element, SR: thiol ligand) generally requires various steps. Therefore, the finding of a new MAu24(SR)18 cluster is not easy though it is necessary to take a great deal of effort to consider the synthesis. In this study, MAu24(SR)18 is searched for and attempted cluster synthesis using a dendrimer-template method. It is also found that this method may be useful for exploring and discovering new clusters.

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用树状大分子寻找掺杂不同元素的硫醇保护金簇
含不同元素(M:不同元素,SR:硫醇配体)的硫醇保护金簇MAu24(SR)18的合成通常需要不同的步骤。因此,发现新的MAu24(SR)18簇并不容易,但需要花费大量的精力来考虑合成。在本研究中,我们搜索了MAu24(SR)18,并尝试使用树突分子模板方法合成簇。该方法还可用于探索和发现新的聚类。
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来源期刊
Macromolecular Chemistry and Physics
Macromolecular Chemistry and Physics 化学-高分子科学
CiteScore
4.30
自引率
4.00%
发文量
278
审稿时长
1.4 months
期刊介绍: Macromolecular Chemistry and Physics publishes in all areas of polymer science - from chemistry, physical chemistry, and physics of polymers to polymers in materials science. Beside an attractive mixture of high-quality Full Papers, Trends, and Highlights, the journal offers a unique article type dedicated to young scientists – Talent.
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