{"title":"Search for Thiol-Protected Gold Clusters Doped with Different Elements Using Dendrimers","authors":"Hisanori Muramatsu, Tetsuya Kambe, Takamasa Tsukamoto, Takane Imaoka, Kimihisa Yamamoto","doi":"10.1002/macp.202400334","DOIUrl":null,"url":null,"abstract":"<p>The synthesis of thiol-protected Au clusters MAu<sub>24</sub>(SR)<sub>18</sub> containing different elements (M: different element, SR: thiol ligand) generally requires various steps. Therefore, the finding of a new <i>M</i>Au<sub>24</sub>(SR)<sub>18</sub> cluster is not easy though it is necessary to take a great deal of effort to consider the synthesis. In this study, <i>M</i>Au<sub>24</sub>(SR)<sub>18</sub> is searched for and attempted cluster synthesis using a dendrimer-template method. It is also found that this method may be useful for exploring and discovering new clusters.</p>","PeriodicalId":18054,"journal":{"name":"Macromolecular Chemistry and Physics","volume":"226 4","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Chemistry and Physics","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/macp.202400334","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The synthesis of thiol-protected Au clusters MAu24(SR)18 containing different elements (M: different element, SR: thiol ligand) generally requires various steps. Therefore, the finding of a new MAu24(SR)18 cluster is not easy though it is necessary to take a great deal of effort to consider the synthesis. In this study, MAu24(SR)18 is searched for and attempted cluster synthesis using a dendrimer-template method. It is also found that this method may be useful for exploring and discovering new clusters.
期刊介绍:
Macromolecular Chemistry and Physics publishes in all areas of polymer science - from chemistry, physical chemistry, and physics of polymers to polymers in materials science. Beside an attractive mixture of high-quality Full Papers, Trends, and Highlights, the journal offers a unique article type dedicated to young scientists – Talent.