William Murrell, Pavel M. Usov, Carol Hua, Fred Pfeffer
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Abstract
Two, semi-linear, fused [n]polynorbornanes based aliphatic ligands (one a di-Methyl ester LMe and the other a di-Ethyl ester LEt) have been synthesised and used to form two isoreticular sql MOFs of the formula [Mn(L)2(NO3)2]. Crystal structure analysis revealed large pores with a distinct lack of interpenetration with the nets neatly aligned to create extended 1D channels. Of interest, the ester moieties of these ligands orient into the channels highlighting the potential for creating customised, pore functionalised MOFs.
期刊介绍：
ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.
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