{"title":"Electrochemical Hydroxyselenenylation of Multifunctional Homoallyl Amines and Ethers","authors":"Wen Xia, Tongtong Liu, Zhipeng Ruan, Pei Tian, Wenxian Yu, Xiaohui Zhang, Yan Xiong","doi":"10.1002/ejoc.202500075","DOIUrl":null,"url":null,"abstract":"A series of β-hydroxyselenides from reactive N-homoallyl(hetero)arylamines and O-homoallyl(hetero)arylethers were effectively synthesized with high to excellent yields under electrolysis. The profiles of mild conditions, simple operation, short time, free of oxidants and transition metals, and good compatibilities of substrates render this methodology greener and potentially synthetic value in producing application. The radical-trapped experiments rationalized the free radical reaction pathway.","PeriodicalId":167,"journal":{"name":"European Journal of Organic Chemistry","volume":"7 1","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/ejoc.202500075","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A series of β-hydroxyselenides from reactive N-homoallyl(hetero)arylamines and O-homoallyl(hetero)arylethers were effectively synthesized with high to excellent yields under electrolysis. The profiles of mild conditions, simple operation, short time, free of oxidants and transition metals, and good compatibilities of substrates render this methodology greener and potentially synthetic value in producing application. The radical-trapped experiments rationalized the free radical reaction pathway.
期刊介绍：
The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry:
Liebigs Annalen
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry.
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