Electrochemical Hydroxyselenenylation of Multifunctional Homoallyl Amines and Ethers

IF 2.7 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2025-02-20 DOI:10.1002/ejoc.202500075
Dr. Wen Xia, Tongtong Liu, Prof. Zhipeng Ruan, Pei Tian, Wenxuan Yu, Ass. Prof. Xiaohui Zhang, Prof. Dr. Yan Xiong
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Abstract

A series of β-hydroxyselenides from reactive N-homoallyl(hetero)arylamines and O-homoallyl(hetero)arylethers were effectively synthesized with high to excellent yields under electrolysis. The profiles of mild conditions, simple operation, short time, free of oxidants and transition metals, and good compatibilities of substrates render this methodology greener and potentially synthetic value in producing application.

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多功能化全烯丙基胺和醚的电化学羟基硒化反应
以反应性n -同丙基(杂)芳胺和o -同丙基(杂)芳醚为原料,在电解条件下高效合成了一系列β-羟基硒化物。该方法具有条件温和、操作简单、时间短、不含氧化剂和过渡金属、与基体相容性好等特点,具有较好的绿色环保和潜在的生产应用价值。自由基捕获实验使自由基反应途径合理化。
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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