Photoreduction Oxidation of Selenides with Isocyanides and Carboxylic Compounds: Access to Selenium-Containing Imides

IF 2.7 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2025-02-21 DOI:10.1002/ejoc.202401029
Ding-Yi Guo, Yan Deng, Xuan-Lin Qin, Yan Pan, Yu-Xuan Liu, Chong-Hui Xu, Yan-Xue Shang, Qing-Wen Gui
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Abstract

A visible light-driven photo oxidation-reduction selenium amidation of selenides with isocyanides and carboxylic compounds for the synthesis of polysubstituted selenium-containing imides is reported. The reaction involves the functionalization of Se−Se bonds under mild conditions by visible light photoredox catalysis with good tolerance of various functionalized group. A possible mechanism has been proposed.

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硒化物与异氰化物和羧基化合物的光还原氧化:获得含硒亚胺
报道了用异氰化物和羧基化合物对硒化物进行可见光光氧化还原硒酰胺化制备多取代含硒亚胺的方法。该反应是在温和条件下通过可见光光氧化还原催化实现Se-Se键的功能化,对各种功能化基团具有良好的耐受性。有人提出了一种可能的机制。
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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