Toward understanding the microbiologically induced crevice corrosion of 90/10 Cu-Ni alloy in the presence of Desulfovibrio vulgaris

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-02-19 DOI:10.1016/j.corsci.2025.112802
Yanan Pu , Zihao Guo , Su Hou , Yue Hou , Congrui Zhu , Fan Feng , Hongbo Zeng , Shougang Chen
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Abstract

The susceptibility of 90/10 Cu-Ni alloy to crevice corrosion induced by Desulfovibrio vulgaris was investigated using a custom-designed crevice structure device under varying media conditions. There was no crevice corrosion in 20 % carbon source (CS) medium inoculated with D. vulgaris, whereas noticeable crevice corrosion occurred in 100 % CS D. vulgaris medium. The uneven distribution of D. vulgaris biofilms between the crevice interior and exterior resulted in localized variations in cathodic species concentration and electrochemical potentials, identified as key factors driving and accelerating crevice corrosion. The deceleration of crevice corrosion in the later stages was attributed to a decline in electrochemical driving force, likely caused by the diminished metabolic activity of D. vulgaris.
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探讨普通脱硫弧菌存在下90/10 Cu-Ni合金的微生物诱导缝隙腐蚀
采用自行设计的缝隙结构装置,研究了90/10 Cu-Ni合金在不同介质条件下对普通脱硫弧菌缝隙腐蚀的敏感性。在20 %碳源(CS)培养基中未见裂缝腐蚀,而在100 %碳源(CS)培养基中出现了明显的裂缝腐蚀。裂缝内外生物膜的不均匀分布导致了阴极物质浓度和电化学电位的局部变化,这是驱动和加速裂缝腐蚀的关键因素。后期裂缝腐蚀的减速归因于电化学驱动力的下降,这可能是由于D. vulgaris的代谢活性降低所致。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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