Dynamic oxide film evolution and corrosion mechanisms of 308L stainless steel in simulated SMR environments

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-02-18 DOI:10.1016/j.corsci.2025.112804
Pengfei Gao , Yanhui Li , Wang Zhu , Jie Qiu , Zhouyang Bai , Qibo Wang , Shaoming Ding
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Abstract

This study investigates the corrosion behavior of 308L stainless steel in simulated small modular reactor boron-free and boron containing environments after exposure of long period. It reveals the twin crystal structures of the porous Fe₃O₄-dominated outer layer and the dynamic transformation of the oxide film components, from Cr₂O₃ in the early stages to FeCr₂O₄ with extended exposure. The mechanism of boron incorporation into the film and its role in enhancing corrosion resistance were also analyzed. These findings elucidate oxide film mechanisms, offering innovative insights for optimizing material design and extending SMR component lifespan under varying water chemistries.
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308L不锈钢在模拟SMR环境中的氧化膜演化及腐蚀机理
研究了308L不锈钢在模拟无硼和含硼小型模块化反应器中长时间暴露后的腐蚀行为。揭示了以Fe₃O₄为主的多孔外层的双晶结构,以及氧化膜组分从早期的Cr₂O₃到随着暴露时间的延长而发生的动态转变。分析了硼在膜中的掺入机理及其对提高膜的耐蚀性的作用。这些发现阐明了氧化膜机制,为优化材料设计和延长SMR组件在不同水化学条件下的使用寿命提供了创新的见解。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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