A MnO2-ZrO2 composite conversion coating to enhance. the corrosion resistance of WE43-T5 Mg alloys

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-02-21 DOI:10.1016/j.corsci.2025.112795
Yi-Jun Lin, Siao-Ying Chen, Wei-Liang Chien, Zong-Syun Yang, Chao-Sung Lin
{"title":"A MnO2-ZrO2 composite conversion coating to enhance. the corrosion resistance of WE43-T5 Mg alloys","authors":"Yi-Jun Lin,&nbsp;Siao-Ying Chen,&nbsp;Wei-Liang Chien,&nbsp;Zong-Syun Yang,&nbsp;Chao-Sung Lin","doi":"10.1016/j.corsci.2025.112795","DOIUrl":null,"url":null,"abstract":"<div><div>Permanganate conversion coating, a potential alternative to chromate conversion coating, was employed on WE43-T5 Mg alloys. A continuous MnO<sub>2</sub>/Mg(OH)<sub>2</sub> coating was observed on the Mg matrix and micrometric second-phase particles (Mg<sub>24</sub>Y<sub>5</sub>, Zr-rich particle). In contrast, no coating formed at grain boundaries, and prolonged immersion resulted in cracks within the grains. These defects were detrimental to the corrosion resistance. A second treatment in ZrF<sub>6</sub><sup>2-</sup> solution healed these defects via ZrO<sub>2</sub> precipitation. This MnO<sub>2</sub>/ZrO<sub>2</sub> composite coating efficiently enhanced the corrosion in 3.5 wt% NaCl, including reduced corrosion current density and corrosion area ratio, and escalated breakdown potential and total impedance.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"248 ","pages":"Article 112795"},"PeriodicalIF":7.4000,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X25001222","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Permanganate conversion coating, a potential alternative to chromate conversion coating, was employed on WE43-T5 Mg alloys. A continuous MnO2/Mg(OH)2 coating was observed on the Mg matrix and micrometric second-phase particles (Mg24Y5, Zr-rich particle). In contrast, no coating formed at grain boundaries, and prolonged immersion resulted in cracks within the grains. These defects were detrimental to the corrosion resistance. A second treatment in ZrF62- solution healed these defects via ZrO2 precipitation. This MnO2/ZrO2 composite coating efficiently enhanced the corrosion in 3.5 wt% NaCl, including reduced corrosion current density and corrosion area ratio, and escalated breakdown potential and total impedance.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
采用MnO2-ZrO2复合转化涂层增强。提高了WE43-T5镁合金的耐腐蚀性能
采用高锰酸盐转化涂层替代铬酸盐转化涂层对WE43-T5镁合金进行了涂层处理。在Mg基体和微米级第二相颗粒(Mg24Y5,富zr颗粒)上观察到连续的MnO2/Mg(OH)2涂层。相反,晶界处未形成涂层,长时间浸泡导致晶粒内部出现裂纹。这些缺陷不利于耐蚀性。在ZrF62溶液中进行二次处理,通过ZrO2沉淀修复了这些缺陷。MnO2/ZrO2复合涂层在3.5 wt% NaCl环境中有效增强了腐蚀,降低了腐蚀电流密度和腐蚀面积比,提高了击穿电位和总阻抗。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
期刊最新文献
Early-stage corrosion sensing via sequential fluorescence from sol-gel and ZnO layers: Self-healing ZIF-8 film-based composite coatings for aluminum alloys Editorial Board Fabrication and corrosion behavior of plasma electrolytic oxidation (PEO) coatings on Zn-deposited carbon steel First-principles insights into the chloride ion-mediated destabilization of cuprous oxide films in aqueous environment Mechanistic insights into γ/γ′-NiPt-diffused coating: Improved oxidation resistance and coating/substrate compatibility
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1