High-performance diamond “Supertools” with extreme tool-life

IF 5.1 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Diamond and Related Materials Pub Date : 2025-02-17 DOI:10.1016/j.diamond.2025.112122
I.S. Durazo-Cardenas , Saurav Goel , P. Shore , L. Kirkwood , Graham L.W. Cross
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Abstract

The use of diamond as a cutting tool is pervasive in modern ultra-high-precision machining applications, particularly for generating sub-micron accurate features through the Single Point Diamond Machining (SPDM) method. Beyond SPDM, diamond is also widely employed in contact profilometry (imaging), nanoindentation, nanoimpact, nanoscratching, and lithography applications.
Interestingly, a particular type of diamond, commonly used in what the fabrication industry calls “supertools,” consistently demonstrates a lifespan up to 300% longer than that of standard diamond tools. Despite this remarkable performance, the reasons behind the enhanced durability of these unique diamond tools have remained unclear.
This paper provides the first experimental explanation for the exceptional properties of these “supertools”. Using Fourier Transform Infrared Spectroscopy (FTIR), we establish that such diamond possess higher overall concentration of nitrogen, particularly Defect Type A (type IaA) and Defect Type C (type Ib). Counterintuitively, they also exhibit lower residual stresses, as revealed through cross-polar examination. Moreover, the diamond tip misalignment error, estimated using Laue backscattering analysis, was found to be insignificant in governing the tool wear resistance. These findings suggest that the wear resistance of natural diamonds can be predicted by screening for high levels of nitrogen defects (combination of Type A and Type C). This insight offers valuable potential for selecting superior diamonds for high-value manufacturing.

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高性能金刚石“超级工具”,具有极高的工具寿命
在现代超高精密加工应用中,金刚石作为切削工具的使用是普遍的,特别是通过单点金刚石加工(SPDM)方法产生亚微米的精确特征。除了SPDM之外,金刚石还广泛应用于接触轮廓测量(成像)、纳米压痕、纳米冲击、纳米划痕和光刻应用。有趣的是,一种特殊类型的钻石,通常用于制造行业所谓的“超级工具”,其使用寿命一直比标准钻石工具长300%。尽管具有如此卓越的性能,但这些独特的金刚石工具耐久性增强背后的原因仍不清楚。本文首次对这些“超级工具”的特殊性质进行了实验解释。利用傅里叶变换红外光谱(FTIR),我们确定了这种金刚石具有较高的总氮浓度,特别是缺陷类型A (IaA型)和缺陷类型C (Ib型)。与直觉相反,它们也表现出较低的残余应力,这是通过交叉极性检查显示的。此外,使用劳埃后向散射分析估计的金刚石尖端不对准误差对刀具耐磨性的影响不显著。这些发现表明,天然钻石的耐磨性可以通过筛选高水平的氮缺陷(A型和C型的组合)来预测。这一见解为为高价值制造选择优质钻石提供了宝贵的潜力。
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来源期刊
Diamond and Related Materials
Diamond and Related Materials 工程技术-材料科学:综合
CiteScore
6.00
自引率
14.60%
发文量
702
审稿时长
2.1 months
期刊介绍: DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.
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