Solvent-Induced Topological Variation in Zn-Triazolate-Dicarboxylate Pillared-Layer Frameworks for Multicomponent Ethylene Purification

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Inorganic Chemistry Pub Date : 2025-02-22 DOI:10.1021/acs.inorgchem.5c00158

Rong Yang, Jian-Wei Cao, Tao Zhang, Weize Wang, Yu Wang, Juan Chen, Kai-Jie Chen

{"title":"Solvent-Induced Topological Variation in Zn-Triazolate-Dicarboxylate Pillared-Layer Frameworks for Multicomponent Ethylene Purification","authors":"Rong Yang, Jian-Wei Cao, Tao Zhang, Weize Wang, Yu Wang, Juan Chen, Kai-Jie Chen","doi":"10.1021/acs.inorgchem.5c00158","DOIUrl":null,"url":null,"abstract":"The exploration of the solvent effect on metal–organic framework (MOF) structure is crucial for promoting their structural chemistry and expanding potential applications. Metal-triazolate-dicarboxylate pillared-layer frameworks, featuring adjustable pore structures, exhibit considerable promise for gas adsorption applications. Under identical conditions, two distinct topological pillared-layer framework structures were successfully synthesized using different solvents: Zn-mfa-atz-rob (rob-type) and Zn-mfa-atz-pcu (pcu-type). In the synthetic process, the solvent serves as a template agent, resulting in substantially different structures. The utilization of H2O/EtOH yielded a rob-type framework, whereas DMF/H2O/MeOH produced the pcu-type framework. Additionally, breakthrough experiments revealed that Zn-mfa-atz-pcu efficiently generated high-purity C2H4 (>99.9%) in a single step at ambient temperature from equimolar quaternary CO2/C2H2/C2H6/C2H4 mixtures.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"24 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.5c00158","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

Abstract

The exploration of the solvent effect on metal–organic framework (MOF) structure is crucial for promoting their structural chemistry and expanding potential applications. Metal-triazolate-dicarboxylate pillared-layer frameworks, featuring adjustable pore structures, exhibit considerable promise for gas adsorption applications. Under identical conditions, two distinct topological pillared-layer framework structures were successfully synthesized using different solvents: Zn-mfa-atz-rob (rob-type) and Zn-mfa-atz-pcu (pcu-type). In the synthetic process, the solvent serves as a template agent, resulting in substantially different structures. The utilization of H₂O/EtOH yielded a rob-type framework, whereas DMF/H₂O/MeOH produced the pcu-type framework. Additionally, breakthrough experiments revealed that Zn-mfa-atz-pcu efficiently generated high-purity C₂H₄ (>99.9%) in a single step at ambient temperature from equimolar quaternary CO₂/C₂H₂/C₂H₆/C₂H₄ mixtures.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.