Effect of Janus balance on the thermal conductivity of nanofluid

IF 3.1 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemical Physics Letters Pub Date : 2025-05-16 Epub Date: 2025-02-22 DOI:10.1016/j.cplett.2025.141969
Takahiro Ikeda , Yusei Kobayashi , Masashi Yamakawa
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Abstract

Nanofluids exhibit enhanced thermal conductivity over conventional fluids. Modification of nanoparticle surfaces with distinct chemical properties (Janus particles) can improve thermal conductivity. Using molecular dynamics, we examined how wetting balances of Janus particles impact thermal conductivity. Our results demonstrate that Janus particles can enhance thermal conductivity more than homogeneous nanoparticles. Interestingly, the excess wetting surface area decreases the enhancement. Structural analysis reveals this change in thermal conductivity correlates with the density of solvents in the interfacial layer around the nanoparticle. Moreover, the dynamics of the nanoparticle do not enhance the thermal conductivity under homogeneous temperature fields.

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Janus平衡对纳米流体导热性的影响
纳米流体表现出比传统流体更强的导热性。对具有不同化学性质的纳米粒子(Janus粒子)表面进行修饰可以改善导热性。利用分子动力学,我们研究了Janus颗粒的润湿平衡如何影响导热性。我们的研究结果表明,Janus颗粒比均匀的纳米颗粒更能提高导热性。有趣的是,多余的润湿表面积降低了增强。结构分析表明,这种导热系数的变化与纳米颗粒周围界面层中溶剂的密度有关。此外,在均匀温度场下,纳米颗粒的动力学并没有提高其导热性。
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来源期刊
Chemical Physics Letters
Chemical Physics Letters 化学-物理:原子、分子和化学物理
CiteScore
5.70
自引率
3.60%
发文量
798
审稿时长
33 days
期刊介绍: Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage. Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
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