{"title":"Effect of Janus balance on the thermal conductivity of nanofluid","authors":"Takahiro Ikeda , Yusei Kobayashi , Masashi Yamakawa","doi":"10.1016/j.cplett.2025.141969","DOIUrl":null,"url":null,"abstract":"<div><div>Nanofluids exhibit enhanced thermal conductivity over conventional fluids. Modification of nanoparticle surfaces with distinct chemical properties (Janus particles) can improve thermal conductivity. Using molecular dynamics, we examined how wetting balances of Janus particles impact thermal conductivity. Our results demonstrate that Janus particles can enhance thermal conductivity more than homogeneous nanoparticles. Interestingly, the excess wetting surface area decreases the enhancement. Structural analysis reveals this change in thermal conductivity correlates with the density of solvents in the interfacial layer around the nanoparticle. Moreover, the dynamics of the nanoparticle do not enhance the thermal conductivity under homogeneous temperature fields.</div></div>","PeriodicalId":273,"journal":{"name":"Chemical Physics Letters","volume":"867 ","pages":"Article 141969"},"PeriodicalIF":2.8000,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009261425001095","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nanofluids exhibit enhanced thermal conductivity over conventional fluids. Modification of nanoparticle surfaces with distinct chemical properties (Janus particles) can improve thermal conductivity. Using molecular dynamics, we examined how wetting balances of Janus particles impact thermal conductivity. Our results demonstrate that Janus particles can enhance thermal conductivity more than homogeneous nanoparticles. Interestingly, the excess wetting surface area decreases the enhancement. Structural analysis reveals this change in thermal conductivity correlates with the density of solvents in the interfacial layer around the nanoparticle. Moreover, the dynamics of the nanoparticle do not enhance the thermal conductivity under homogeneous temperature fields.
期刊介绍:
Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage.
Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.